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Effect of TiO2 Coating Thickness on Photovoltaic Performance of Dye-sensitized Solar Cells Prepared by Screen-printing Using TiO2 Powders

  • Lee, Deuk Yong (Department of Biomedical/Materials Engineering, Daelim University) ;
  • Cho, Hun (Department of Biomedical/Materials Engineering, Daelim University) ;
  • Kang, Daejun (Department of Biomedical/Materials Engineering, Daelim University) ;
  • Kang, Jong-Ho (Energy and Environmental Division, KICET) ;
  • Lee, Myung-Hyun (Energy and Environmental Division, KICET) ;
  • Kim, Bae-Yeon (Department of Advanced Materials Engineering, Incheon National University) ;
  • Cho, Nam-Ihn (Department of Electronic Engineering, Sun Moon University)
  • Received : 2014.06.02
  • Accepted : 2014.07.02
  • Published : 2014.07.31

Abstract

Dye-sensitized solar cells (DSSCs) were synthesized using a $0.25cm^2$ area of a $TiO_2$ nanoparticle layer as the electrode and platinum (Pt) as the counter electrode. The $TiO_2$ nanoparticle layers (12 to 22 ${\mu}m$) were screen-printed on fluorine-doped tin oxide glass. Glancing angle X-ray diffraction results indicated that the $TiO_2$ layer is composed of pure anatase with no traces of rutile $TiO_2$. The Pt counter electrode and the ruthenium dye anchored $TiO_2$ electrode were then assembled. The best photovoltaic performance of DSSC, which consists of a $18{\mu}m$ thick $TiO_2$ nanoparticle layer, was observed at a short circuit current density ($J_{sc}$) of $14.68mA{\cdot}cm^{-2}$, an open circuit voltage ($V_{oc}$) of 0.72V, a fill factor (FF) of 63.0%, and an energy conversion efficiency (${\eta}$) of 6.65%. It can be concluded that the electrode thickness is attributed to the energy conversion efficiency of DSSCs.

Keywords

References

  1. M. Y. Song, D. K. Kim, K. J. Ihn, S. M. Jo, and D. Y. Kim, "Electrospun $TiO_2$ Electrodes for Dye-sensitized Solar Cells," Nanotechnol.,15 [12] 1861-65 (2004). https://doi.org/10.1088/0957-4484/15/12/030
  2. K. Fujuhara, A. Kumar, R. Jose, S. Ramakrishna, and S. Uchida, "Spray Deposition of Electrospun $TiO_2$ Nanorods for Dye-sensitized Solar Cell," Nanotechnol.,18 [36] 365709 (2007). https://doi.org/10.1088/0957-4484/18/36/365709
  3. K. Onozuka, B. Ding, Y. Tsuge, T. Naka, M. Yamazaki, S. Sugi, S. Ohno, M. Yoshikawa, and S. Shiratori, "Electrospinning Processed Nanofibrous $TiO_2$ Membranes for Photovoltaic Applications," Nanotechnol., 17 [4] 1026-31 (2006). https://doi.org/10.1088/0957-4484/17/4/030
  4. S. Ito, P. Chen, P. Comte, M. K. Nazeeruddin, P. Liska, P. Pechy, and M. Grazel, "Fabrication of Screen-printing Pastes from $TiO_2$ Powders for Dye-sensitized Solar Cells," Prog. Photovol. Res. Appl., 15 [7] 603-12 (2007). https://doi.org/10.1002/pip.768
  5. M. Gomez, E. Magnusson, E. Olsson, A. Hagfeldt, S. E. Lindquist, and C. G. Granqvist, "Nanocrystalliane Ti-oxidebased Solar Cells Made by Sputter Deposition and Dye Sensitization: Efficiency Versus Film Thickness," Sol. Energy Mater. Sol. Cells, 62 259-63 (2000). https://doi.org/10.1016/S0927-0248(99)00167-1
  6. N. Sato, K. Nakajima, N. Usami, H. Takahashi, A. Muramatsu, and E. Matsubara, "Preparation of a $TiO_2$ Film Coated Si Device for Photo-decomposition of Water by CVD Method Using $Ti(OPri)_4$," Mater. Trans., 43 1533-36 (2002). https://doi.org/10.2320/matertrans.43.1533
  7. D. Y. Lee, J. Cho, M. Lee, N. Cho, and Y. Song, "Insertion of a $TiO_2$ Buffer Layer for the Fixation of Electrospun $TiO_2$ Nanofibers on Glass Substrates,"J. Kor. Phys. Soc., 55 [1] 84-88 (2009). https://doi.org/10.3938/jkps.55.84
  8. Y. Kim, I. Lee, Y. Song, M. Lee, B. Kim, N. Cho, and D.Y. Lee, "Influence of $TiO_2$ Coating Thickness on Energy Conversion Efficiency of Dye-sensitized Solar Cell," Electron. Mater. Lett., 10 [2] 445-49 (2014). https://doi.org/10.1007/s13391-013-3194-z
  9. D. Y. Lee, J. Kim, Y. Kim, I. Lee, M. Lee, and B. Kim, "Bond Strength of $TiO_2$ Coatings onto FTO Glass for Dyesensitized Solar Cell," J. Sensor Sci. Technol., 21 [6] 395-401 (2012). https://doi.org/10.5369/JSST.2012.21.6.395
  10. D. Y. Lee, B. Kim, S. Lee, M. Lee, Y. Song, and J. Lee, "Titania Nanofibers Prepared by Electrospinning," J. Kor. Phys. Soc., 48 [6] 1686-90 (2006).
  11. S. W. Lee, K. K. Kim, Y. Cui, S. C. Lim, Y. W. Cho, S. M. Kim, and Y. H. Lee, "Adhesion Test of Carbon Nanotube Film Coated onto Transparent Conducting Substrates," Nano, 5 133-38 (2010). https://doi.org/10.1142/S1793292010002025
  12. S. Ito, P. Chen, P. Comte, M. K. Nazeeruddin, P. Liska, P. Pechy, and M. Gratzel, "Fabrication of Screen-printing Pastes from $TiO_2$ Powders for Dye-sensitized Solar Cells," Prog. Photovol.: Res. Appl., 15 [7] 603-12 (2007). https://doi.org/10.1002/pip.768
  13. R. Zhu, C. Jiang, X. Liu, B. Liu, A. Kumar, and S. Ramakrishna, "Improved Adhesion of Interconnected $TiO_2$ Nanofiber Network on Conductive Substrate and Its Application in Polymer Photovoltaic Devices," Appl. Phys. Lett., 93 013102 (2008). https://doi.org/10.1063/1.2907317
  14. J. Greulich, M. Glatthaar, and S. Rein, "Fill Factor Analysis of Solar Cells' Current-Voltage Curves," Prog.Photovol.: Res. Appl., 18 [7] 511-15 (2010). https://doi.org/10.1002/pip.979
  15. S. R. Kim, M. K. Parvez, and M. Chhowalla, "UV-reduction of Graphene Oxide and Its Application As an Interfacial Layer to Reduce the Back-transport Reactions In Dye-sensitized Solar Cells," Chem. Phys. Lett., 483 [1-3] 124-27 (2009). https://doi.org/10.1016/j.cplett.2009.10.066
  16. U. Bach, D. Lupo, P. Comte, J. E. Moser, F. Welssortel, J. Salbeck, H. Spreitzer, and M. Graztel, "Solid-state Dyesensitized Mesoporous $TiO_2$ Solar Cells with High Photonto-electrons Conversion Efficiencies," Nature, 395 583-85 (1998). https://doi.org/10.1038/26936