상하수도학회지 (Journal of Korean Society of Water and Wastewater)

  • 제30권4호
  • /
  • Pages.409-415
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  • 2016
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  • 1225-7672(pISSN)
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  • 2287-822X(eISSN)
대한상하수도학회 (The Korean Society of Water and Wastewater)
권호 표지
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인 흡착용 마그네타이트 합성 시 알칼리 종류 및 농도가 공침 입자크기에 미치는 영향

Effects of alkali species and concentration on the size distribution of the co-precipitated magnetite particles used for phosphate adsorption

  • 투고 : 2016.07.20
  • 심사 : 2016.07.28
  • 발행 : 2016.08.15
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초록

Magnetite particles were synthesized by co-precipitation of water-soluble 밀 스케일-derived precursor by various concentrations of (0.5, 0.67, 1, 2 N) NaOH and (0.6, 0.8, 1.2, 2.4 N) $NH_4OH$. It is theoretically known that as the concentration of the alkaline additive used in iron oxide synthesis increases, the particle size distribution of that iron oxide decreases. This trend was observed in both kind of alkaline additive used, NaOH and $NH_4OH$. In addition, the magnetite synthesized in NaOH showed a relatively smaller particle size distribution than magnetite synthesized in $NH_4OH$. Crystalline phase of the synthesized magnetite were determined by X-ray diffraction spectroscopy(XRD). The particles were then used as an adsorbent for phosphate(P) removal. Phosphorus adsorption was found to be more efficient in NaOH-based synthesized magnetite than the $NH_4OH$-based magnetite.

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참고문헌

  1. Adriano, F. D. S., Tiago, P. B., Elis, C. C. G., Antoninho V., Elisane, L. (2012) Adsorption of phosphate using mesoporous spheres containing iron and aluminum oxide, Chemical Engineering Journal, 210, pp. 143-149. https://doi.org/10.1016/j.cej.2012.08.080
  2. Ahn, T., Kim, J. H., Yang, H. M., Lee, J. W., Kim, J. D. (2012). Formation Pathways of Magnetite Nanoparticles by Coprecipitation Method. Journal of Physical Chemistry, 116, pp. 6069-6076.
  3. Buzin, P. J. W. K. D., Vigânico, E. M., Silva, R. D. A., Heck, N. C., Schneider, I. A., Menezes, J. C. S. D. S. (2014) Prodution of Ferrous Sulfate From Steelmaking 밀 스케일, International Journal of Scientific & Engineering Research, 5(4), pp. 353-359
  4. Chen, R. Y., Yuen, W. Y. D. (2001) Oxide-Scale Structures Formed on Commercial Hot-Rolled Steel Strip and Their Formation Mechanisms, Oxidation of Metals, 56(1), pp. 89-118 https://doi.org/10.1023/A:1010395419981
  5. Choi, Y., San, P., Doliente, J. E., Maeng, M., Dockko, S., Choi, E. (2016). Adsorptive removal of arsenate using inorganic magnetite particles. Desalination and Water Treatment, pp. 1-9
  6. Chun, H. C., Choi. Y. G. (2015) A Study on the 밀 스케일 Pretreatment and Magnetite Production for Phosphate Adsorption, Journal of Korean Society of Environment Engineering, 37(4), pp. 246-252. https://doi.org/10.4491/KSEE.2015.37.4.246
  7. Daou, T. J., Begin-Colin, S., Greneche, J. M., Thomas F., Derory, A., Bernhardt, P., Legare, P., Pourroy, G. (2007). Phosphate adsorption properties of magnetite-based nanoparticles. Chemistry of Materials, 19, pp. 4494-4505. https://doi.org/10.1021/cm071046v
  8. Gnanaprakash, G., Mahadevan, S., Jayakumar, T., Kalyanasundaram, P., Philip, J., Raj, B. (2007). Effect of initial pH and temperature or iron salt solutions on formation of magnetite nanoparticles. Materials Chemistry and Physics, 103, pp. 168-175 https://doi.org/10.1016/j.matchemphys.2007.02.011
  9. Kim, J. H., Lim, C. S., Kim, K. Y., Kim, D. K., Lee, S. I., Kim, J. S. (2008) Application of Adsorption Characteristic of Ferrous Iron Waste to Phosphate Removal from Municipal Wastewater, Korean Journal of Environmental Agriculture 27(3), pp. 231-238. https://doi.org/10.5338/KJEA.2008.27.3.231
  10. Lee, S. M. Ahn, J. E. (2015) Comparison of Phosphate Recovery Potential from Alum, PAC, FeSO4 Coagulation Sludge and Return Sludge Ash using Various Chemical Agents, Journal of the Korean Society of Urban Environment, 15(2), pp. 133-140
  11. Legodi, M. A., Waal, D. D. (2007) The preparation of magnetite, goethite, hematite and maghemite of pigment quality from 밀 스케일 iron waste, Dyes and Pigments, 78(1), pp. 161-168
  12. Richard J. H., Andrew P. (1996) Magnetic properties of the magnetite-spinel solid solution : Curie temperatures, magnetic susceptibilities and cation ordering, American Mineralogist, 81, pp. 375-384 https://doi.org/10.2138/am-1996-3-412
  13. Safaa, M. R. (2013) Phosphate removal from aqueous solution using slag and fly ash, Housing and Building National Research Center, 9(3), pp 270-275
  14. Suslick, K. S., Fang, M., Hyeon, T. (1996). Sonochemical synthesis of iron colloids. Journal of the American Chemical Society, 118, pp. 11960-11961 https://doi.org/10.1021/ja961807n
  15. Yoon, S. Y., Lee, C. G., Park, J. A., Kim, J. H., Kim, S. B., Lee, S. H., Choi, J. W. (2014). Kinetic, equilibrium and thermodynamic studies for phosphate adsorption to magnetic iron oxide particles. Chemical Engineering Journal, 236, pp. 341-347. https://doi.org/10.1016/j.cej.2013.09.053
  16. Zeng, L., Li, X., Liu, J. (2004). Adsorptive removal of phosphate from aqueous solutions using iron oxide tailings. Water Research, 38, pp. 1318-1326. https://doi.org/10.1016/j.watres.2003.12.009