Korean Journal of Materials Research (한국재료학회지)

Materials Research Society of Korea (한국재료학회)
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Effect of B2O3 Addition on Thermal, Structure, and Sealing Properties V2O5-P2O5-ZnO Glass

B2O3첨가에 따른 V2O5-P2O5-ZnO계 유리의 물성 및 구조와 봉착특성

  • Sung, Aram (Department of Materials Science and Engineering, Inha University) ;
  • Kim, Yurian (Department of Materials Science and Engineering, Inha University) ;
  • Kim, Hyungsun (Department of Materials Science and Engineering, Inha University)
  • Received : 2016.07.11
  • Accepted : 2016.09.02
  • Published : 2016.10.27
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Abstract

We have investigated a glass-forming region of $V_2O_5-P_2O_5-ZnO$ glass and the effects of the addition of modifier oxides ($B_2O_3$) to the glass systems as a sealing material to improve the adhesion between the glass frits and a soda lime substrate. Thermal properties and coefficient of thermal expansion were measured using a differential scanning calorimetry, a dilatometer and a hot stage microscopy. Structural changes and interfacial reactions between the glass substrate and the glass frit after sintering (at $400^{\circ}C$ for 1 h) were measured by Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy and scanning electron microscope. The results showed that the adhesion strength increases as the content of $B_2O_3$ at 5 mol% increases because of changes in the structural properties. It seems that the glass structures change with $B_2O_3$, and the $Si^{4+}$ ions from the substrate are diffused to the sealing glass. From these results, we could understand the mechanism of strengthening of the adhesion of soda lime silica substrate by ion-diffusion from the substrate to the glass.

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References

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