DOI QR코드

DOI QR Code

직접 접촉식막증발을 이용한 셰일가스 발생수의 처리에서 스케일 형성에 의한 막오염 경향 분석

Analysis of Fouling Propensity due to Scale Formation in the Treatment of Shale Gas Produced Water Using Direct Contact Membrane Distillation (DCMD)

  • 신용현 (국민대학교 건설시스템공학과) ;
  • 고영훈 (국민대학교 건설시스템공학과) ;
  • 최용준 (국민대학교 건설시스템공학과) ;
  • 이상호 (국민대학교 건설시스템공학과) ;
  • 손진식 (국민대학교 건설시스템공학과)
  • Shin, Yonghyun (School of Civil and Environmental Engineering, Kookmin University) ;
  • Ko, Younghoon (School of Civil and Environmental Engineering, Kookmin University) ;
  • Choi, Yongjun (School of Civil and Environmental Engineering, Kookmin University) ;
  • Lee, Sangho (School of Civil and Environmental Engineering, Kookmin University) ;
  • Sohn, Jinsik (School of Civil and Environmental Engineering, Kookmin University)
  • 투고 : 2016.05.31
  • 심사 : 2016.08.30
  • 발행 : 2016.10.31

초록

Shale gas has become increasingly important as a viable alternative to conventional gas resources. However, one of the critical issues in the development of shale gas is the generation of produced water, which contains high concentration of ionic compounds (> TDS of 100,000 mg/L). Accordingly, membrane distillation (MD) was considered to treat such produced water. Experiments were carried out using a laboratory-scale direct contact MD (DCMD). Synthetic produced water was prepared to examine its fouling propensity in MD process. Antiscalants and in-line filtration were applied to control fouling by scale formation. Fouling rates (-dJ/dt) were calculated for in-depth analysis of fouling behaviors. Results showed that severe fouling occurred during the treatment of high range produced water (TDS of 308 g/L). Application of antiscalant was not effective to retard scale formation. On the other hand, in-line filtration increased the induction time and reduced fouling.

키워드

참고문헌

  1. JENKINS, C D, BOYER, C M,2008,Coalbed andshale gasreservoirs, JPT,2012, Vol. 60, pp. 92-99.
  2. X. Zhang, A.Y. Sun, and I.J. Duncan, Shale gas wastewater management under uncertainty. Journal of Environmental Management, 165, 2016, pp. 188-198. https://doi.org/10.1016/j.jenvman.2015.09.038
  3. L.D. Tijing, Y.C. Woo, J.-S. Choi, S. Lee, S.-H. Kim, and H.K. Shon, 2015,Fouling and its control in membrane distillation-A review. JMS, 475, pp. 215-244
  4. S. Lee, J. Kim, and C.-H. Lee, 1999,Analysis of $CaSO_4$ scale formation mechanism in various nanofiltration modules. JMS, 163(1), pp. 63-74.
  5. S.A. Ali, I.W. Kazi, and F. Rahman, 2015,Synthesis and evaluation of phosphate-free antiscalants to control $CaSO_4$.$2H_2O$ scale formation in reverse osmosis desalination plants. Desal, 357, pp. 36-44. https://doi.org/10.1016/j.desal.2014.11.006
  6. A. Alkhudhiri, N. Darwish, N. Hilal, 2012, "Membranedistillation: A comprehensive review," Desal 287, pp. 2-18. https://doi.org/10.1016/j.desal.2011.08.027