Environmental Engineering Research

  • 제22권4호
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  • Pages.384-392
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  • 2017
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  • 1226-1025(pISSN)
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  • 2005-968X(eISSN)
대한환경공학회 (Korean Society of Environmental Engineers)
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Comparative adsorption of crude oil using mango (Mangnifera indica) shell and mango shell activated carbon

  • 투고 : 2017.01.23
  • 심사 : 2017.05.19
  • 발행 : 2017.12.31
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초록

Mango shell (MS) and mango shell activated carbon (MSAC) was used to adsorb crude oil from water at various experimental conditions. The MSAC was prepared by carbonization at $450^{\circ}C$ and chemical activation using strong $H_3PO_4$ acid. The adsorbents were characterized with Fourier Transform Infrared spectroscopy. Investigations carried out included the effects of parametric variations of different adsorbate dose, adsorbent dose, time, temperature, pH and mixing speed on the adsorption of crude oil. The equilibrium isotherm for the adsorption process was determined using Langmuir, Freundlich, Temkin and Dubinin Radushkevich isotherm models. Temkin isotherm was found to fit the equilibrium data reasonably well than others. The result demonstrated that MSAC was more effective for crude oil adsorption than raw mango shell. Optimum conditions were also presented. The enhanced effect from activation was justified statistically using Analysis of Variance and Bonferroni-Holm Posthoc significance test. The pseudo first order kinetics gave a better fit for crude oil adsorption with both MS and MSAC.

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