DOI QR코드

DOI QR Code

비정질 텔루륨 산화물 박막 특성에 미치는 O2/Ar 가스비율의 영향

Effect of O2/Ar Gas Ratios on the Characteristics of Amorphous Tellurium Oxide Thin Films

  • 공헌 (전남대학교 신화학소재공학과) ;
  • 정건홍 (전남대학교 신화학소재공학과) ;
  • 여종빈 (전남대학교 촉매연구소) ;
  • 이현용 (전남대학교 신화학소재공학과)
  • Kong, Heon (Department of Advanced Chemicals and Engineering, Chonnam National University) ;
  • Jung, Gun-Hong (Department of Advanced Chemicals and Engineering, Chonnam National University) ;
  • Yeo, Jong-Bin (Research Institute of Catalysis, Chonnam National University) ;
  • Lee, Hyun-Yong (Department of Advanced Chemicals and Engineering, Chonnam National University)
  • 투고 : 2017.01.06
  • 심사 : 2017.03.08
  • 발행 : 2017.05.01

초록

$TeO_x$ thin films were deposited at various $O_2$/Ar gas-flow ratios by a reactive RFmagneton sputtering technique from $TeO_2$ and Te targets. X-ray diffraction (XRD) results revealed that the $TeO_x$ thin films were amorphous. The structure and chemical composition of the $TeO_x$ thin films were investigated by fourier transform infrared spectroscopy (FT-IR) and X-ray photoelectron spectroscopy (XPS). The optical characteristics of the $TeO_x$ thin films were investigated by an Ellipsometer and a UV-VIS-NIR spectrophotometer. According to the $O_2$/Ar gas-flow ratios, the atomic composition ratio of $TeO_x$ thin films was divided into two regions(x=1-2, 2-3). Different optical characteristics were shown in each region. With an increasing $O_2$/Ar gas-flow ratio, the refractive index of the $TeO_x$ thin films decreased and the optical bandgap of the films increased.

키워드

참고문헌

  1. A. Mecseki, I. Foldvari, and R. Voszka, Acta Phys. Acad. Sci. Hung., 53, 15 (1982). [DOI: https://dx.doi.org/10.1007/BF03156172]
  2. I. Abdulhalim, C. N. Pannell, J. Wang, G. Wylangowski, and D. N. Payne, J. Appl. Phys., 75, 519 (1994). [DOI: http://dx.doi.org/10.1063/1.355832]
  3. T. Yano, A. Fukumoto, and A. Watanabe, J. Appl. Phys., 42, 3674 (1971). [DOI: http://dx.doi.org/10.1063/1.1659667]
  4. V. M. Kotov, G. N. Shkerdin, D. G. Shkerdin, and E. V. Kotov, J. Opt. Technol., 72, 511 (2005). [DOI: https://doi.org/10.1364/JOT.72.000511]
  5. R. Nayak, V. Gupta, A. L. Dawar, and K. Sreenivas, Thin Solid Films, 445, 118 (2003). [DOI: http://dx.doi.org/10.1016/S0040-6090(03)01284-7]
  6. N. Dewan, V. Gupta, K. Sreenivas, and R. S. Katiyar, J. Appl. Phys., 101, 084910 (2007). [DOI: http://dx.doi.org/10.1063/1.2717139]
  7. M. Takenaga, N. Yamada, K. Nishiuchi, N. Akahira, T. Ohta, S. Nakamura, and T. Yamashita, J. Appl. Phys., 54, 5376 (1983). [DOI: http://dx.doi.org/10.1063/1.332716]
  8. S. M. Pietralunga, M. Lanata, M. Fere, D. Piccinin, G. Cusmai, M. Torregiani, and M. Martinelli, Opt. Express, 16, 21662 (2008). [DOI: https://doi.org/10.1364/OE.16.021662]
  9. K. Arshak and O. Korostynska, Sensors, 2, 347 (2002). [DOI: https://dx.doi.org/10.3390/s20800347]
  10. T. Siciliano, M. D. Giulio, M. Tepore, E. Filippo, G. Micocci, and A. Tepore, Sens. Actuators, B., 138, 550 (2009). [DOI: http://dx.doi.org/10.1016/j.snb.2009.02.068]
  11. T. Siciliano, M. D. Giulio, M. Tepore, E. Filippo, G. Micocci, and A. Tepore, Vacuum, 84, 935 (2010). [DOI: http://dx.doi.org/10.1016/j.vacuum.2009.12.017]
  12. M. F. Al-Kuhaili, S.M.A. Durrani, E. E. Khawaja, and J. Shirokoff, J. Phys. D: Appl. Phys., 35, 910 (2002). https://doi.org/10.1088/0022-3727/35/9/312
  13. S.N.B. Hodgson and L. Weng, J. Sol-Gel Sci. Technol., 18, 145 (2000). [DOI: 10.1023/A:1008717003930]
  14. N. Dewan, K. Sreenivas, and V. Gupta, J. Cryst. Growth, 305, 237 (2007). [DOI: http://dx.doi.org/10.1016/j.jcrysgro.2007.03.054]
  15. L. I. Qinghui, G. U. Donghong, and G.A.N. Fuxi, J. Mater. Sci. Technol., 20, 678 (2004).
  16. N. Uchida, Phys. Rev. B., 4, 3736 (1971). [DOI: https://doi.org/10.1103/PhysRevB.4.3736]
  17. M. D. Giulio, R. Rella, P. Siciliano, and S. Cucurachi, Vacuum, 43, 305 (1992). [DOI: http://dx.doi.org/10.1016/0042-207X(92)90161-O]
  18. A. Mansingh and S. Kumar, Thin Solid Films, 161, 101 (1988). [DOI: http://dx.doi.org/10.1016/0040-6090(88)90240-4]
  19. S.K.J. Al-Ani and C. A. Hogarth, Int. J. Electron., 58, 123 (1985). [DOI: http://dx.doi.org/10.1080/00207218508939009]