DOI QR코드

DOI QR Code

Ferrate(VI)를 이용한 발전소 탈황폐수 처리에 관한 연구

A study on the desulfurization wastewater treatment using Ferrate(VI)

  • 조은영 (한국산업기술시험원 환경기술본부 환경융합기술센터) ;
  • 박찬규 (한국산업기술시험원 환경기술본부 환경융합기술센터)
  • Jo, Eun-young (Environmental convergence technology center, Department of environmental engineering, Korea Testing Laboratory) ;
  • Park, Chan-gyu (Environmental convergence technology center, Department of environmental engineering, Korea Testing Laboratory)
  • 투고 : 2017.06.15
  • 심사 : 2017.08.01
  • 발행 : 2017.08.29

초록

Wastewater treatment using ferrate (VI) solution is becoming a promising technology for several years, because it is high efficient and harmless technology. In this study, the ferrate (VI) solution was tested to treatment of desulfurization wastewater. The effluent from desulfurization wastewater treatment process of power plant was used as raw water, and the COD and T-N removal efficiency of ferrate(VI) solution were investigated. In the test, as the injection rate increased from 0.1 to 1.0%, the removal efficiency of COD also slightly increased, about 80% of COD were removed in 1.0% of injection rate. In the case of T-N, about 50% of T-N was removed in the condition of 1.0% of injection rate. The removal efficiency of COD and T-N also affected by reaction time, maximum removal efficiency was shown in 30 min of treatment. From these results, the wastewater treatment with ferrate(VI) solution can be great solutions for treatment of non-biodegradable pollutants in wastewater, especially for the 3rd treatment of wastewater.

키워드

참고문헌

  1. Al-Abduly, A., and Sharma, V. K. (2014). Oxidation of benzothiophene, dibenzothiophene, and methyldibenzothiophene by ferrate (VI). Journal of hazardous materials, 279, 296-301. https://doi.org/10.1016/j.jhazmat.2014.06.083
  2. Barisci, S., Ulu, F., Sillanpaa, M., and Dimoglo, A. (2016). The usage of different forms of ferrate (VI) ion for amoxicillin and ciprofloxacin removal: density functional theory based modelling of redox decomposition. Journal of chemical technology and biotechnology, 91(1), 257-266. https://doi.org/10.1002/jctb.4625
  3. Cha, G. E., Noh, D. J., Seo, J. H., Lim, J. H., Lee, T. Y., & Lee, J. K. (2013). Electrochemical Treatment of COD and TN in Wastewater from Flue Gas Desulfurization Process. Journal of Environmental Science International, 22(9), 1073-1078. https://doi.org/10.5322/JESI.2013.22.9.1073
  4. Esplugas, S., Yue, P. L., & Pervez, M. I. (1994). Degradation of 4-chlorophenol by photolytic oxidation. Water Research, 28(6), 1323-1328. https://doi.org/10.1016/0043-1354(94)90297-6
  5. Gan, W., Sharma, V. K., Zhang, X., Yang, L., and Yang, X. (2015). Investigation of disinfection byproducts formation in ferrate (VI) pre-oxidation of NOM and its model compounds followed by chlorination. Journal of hazardous materials, 292, 197-204. https://doi.org/10.1016/j.jhazmat.2015.02.037
  6. Gulberlet, H., Finkler, S., Paetsch, B., Van Eldik, R., and Prinsloo, F. (1996). Formation of Sulphur Compounds and Sulphur-Nitrogen Compounds in Flue Gas Desulphurization Systems and Their Influence on the Kinetics of Sulphite Oxidation. VGB KRAFTWERKSTECHNIK-ENGLISH EDITION-, 76, 126-133.
  7. Jain, A., Sharma, V. K., and Mbuya, O. S. (2009). Removal of arsenite by Fe (VI), Fe (VI)/Fe (III), and Fe (VI)/Al (III) salts: Effect of pH and anions. Journal of hazardous materials, 169(1), 339-344. https://doi.org/10.1016/j.jhazmat.2009.03.101
  8. Jiang, W., Chen, L., Batchu, S. R., Gardinali, P. R., Jasa, L., Marsalek, B., and Sharma, V. K. (2014). Oxidation of microcystin-LR by ferrate (VI): kinetics, degradation pathways, and toxicity assessments. Environmental science & technology, 48(20), 12164-12172. https://doi.org/10.1021/es5030355
  9. Jo, E. Y., Lee, T. K., Kim, Y., and Park, C. G. (2016). Effect of anions on the removal of bisphenol A in wastewater by electro-oxidation process. Desalination and Water Treatment, 57(60), 29500-29508. https://doi.org/10.1080/19443994.2016.1197156
  10. Karlesa, A., De Vera, G. A. D., Dodd, M. C., Park, J., Espino, M. P. B., and Lee, Y. (2014). Ferrate (VI) oxidation of $\beta$-lactam antibiotics: reaction kinetics, antibacterial activity changes, and transformation products. Environmental science & technology, 48(17), 10380-10389. https://doi.org/10.1021/es5028426
  11. Kim, C., Panditi, V. R., Gardinali, P. R., Varma, R. S., Kim, H., and Sharma, V. K. (2015). Ferrate promoted oxidative cleavage of sulfonamides: kinetics and product formation under acidic conditions. Chemical Engineering Journal, 279, 307-316. https://doi.org/10.1016/j.cej.2015.04.139
  12. Kim I. K. (2015) Degradation of perchloroethylene by ferrate(VI), Journal of Korean society of water and wastewater, 29(1), pp. 39-46. https://doi.org/10.11001/jksww.2015.29.1.039
  13. Lee Y. H. (2017) A study on the treatment of organic compound and phosphorus in sewage using ferrate(VI), The Graduate shool of Gwangwoon University.
  14. Masten, S. J., & Davies, S. H. (1994). The use of ozonation to degrade organic contaminants in wastewaters. Environmental science & technology, 28(4), 180A-185A. https://doi.org/10.1021/es00053a718
  15. Nam J. H., Kwon B. H., and Kim I. K. (2012) Degradation of trichloroethylene in aqueous phase by electrochemical ferrate(VI), Journal of Korean Society of Water and Wastewater. 26(3), pp. 453-461. https://doi.org/10.11001/jksww.2012.26.3.453
  16. Park, C. G., Jo, E. Y., Park, S. M., Jeon, H. W., and Ko, K. B. (2015). Degradation of bisphenol A by UV/$H_2O_2$ oxidation in aqueous solution containing nitrate and alkalinity. Desalination and Water Treatment, 54(4-5), 1022-1028. https://doi.org/10.1080/19443994.2014.952671
  17. Prucek, R., Tucek, J., Kolarik, J., Huskova, I., Filip, J., Varma, R. S. and Zboril, R. (2015). Ferrate (VI)-prompted removal of metals in aqueous media: mechanistic delineation of enhanced efficiency via metal entrenchment in magnetic oxides. Environmental science & technology, 49(4), 2319-2327.. https://doi.org/10.1021/es5048683
  18. Sailo, L., Pachuau, L., Yang, J. K., Lee, S. M., and Tiwari, D. (2015). Efficient use of ferrate (VI) for the remediation of wastewater contaminated with metal complexes. Environmental Engineering Research, 20(1), 89-97. https://doi.org/10.4491/eer.2014.079
  19. Sharma V. K. (2002), Potassium ferrate(VI): an environmentally friendly oxidant, Advances in Environmental Research, 6(2), pp. 143-156. https://doi.org/10.1016/S1093-0191(01)00119-8
  20. Sharma, V. K. (2007). Disinfection performance of Fe (VI) in water and wastewater: a review. Water science and Technology, 55(1-2), 225-232. https://doi.org/10.2166/wst.2007.019
  21. Sharma, V. K., Li, X. Z., Graham, N., and Doong, R. A. (2008). Ferrate (VI) oxidation of endocrine disruptors and antimicrobials in water. Journal of water supply: research and technology-AQUA, 57(6), 419-426. https://doi.org/10.2166/aqua.2008.077
  22. Sharma, V. K., Zboril, R., and McDonald, T. J. (2014). Formation and toxicity of brominated disinfection byproducts during chlorination and chloramination of water: A review. Journal of Environmental Science and Health, Part B, 49(3), 212-228. https://doi.org/10.1080/03601234.2014.858576
  23. Sun, X., Zhang, Q., Liang, H., Ying, L., Xiangxu, M., and Sharma, V. K. (2016). Ferrate (VI) as a greener oxidant: Electrochemical generation and treatment of phenol. Journal of hazardous materials, 319, 130-136. https://doi.org/10.1016/j.jhazmat.2015.12.020
  24. Wulfsberg, G. (1991). Principles of descriptive inorganic chemistry. University Science Books.
  25. Zhou, Z., and Jiang, J. Q. (2015). Treatment of selected pharmaceuticals by ferrate (VI): Performance, kinetic studies and identification of oxidation products. Journal of pharmaceutical and biomedical analysis, 106, 37-45. https://doi.org/10.1016/j.jpba.2014.06.032