한국세라믹학회지 (Journal of the Korean Ceramic Society)

  • 제55권4호
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  • Pages.358-363
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  • 2018
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  • 1229-7801(pISSN)
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  • 2234-0491(eISSN)
한국세라믹학회 (The Korean Ceramic Society)
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Pr2NiO4+δ for Cathode in Protonic Ceramic Fuel Cells

  • An, Hyegsoon (High-temperature Energy Materials Research Center, Korea Institute of Science and Technology) ;
  • Shin, Dongwook (Department of Fuel Cells and Hydrogen Technology, Hanyang University) ;
  • Ji, Ho-Il (High-temperature Energy Materials Research Center, Korea Institute of Science and Technology)
  • 투고 : 2018.04.13
  • 심사 : 2018.05.29
  • 발행 : 2018.07.31
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초록

To improve the polarization property of cathodes, which is the main factor limiting the performance of protonic ceramic fuel cells (PCFCs), $K_2NiF_4-type$ $Pr_2NiO_{4+{\delta}}$, which is expected to exhibit a triple conducting property (proton, oxygen ion, and hole conductions) was applied to PCFCs and its properties were investigated. Low-temperature microwave heat-treatment was used to achieve both sufficient interface adhesion between the electrolyte and the cathode layers and suppression of the secondary phase formation due to migration of elements such as barium and cerium. Through this fabrication method, a high performance of $0.82W{\cdot}cm^{-2}$ and low ohmic resistance of $0.06{\Omega}{\cdot}cm^2$ were obtained in an $Ni-BaCe_{0.55}Zr_{0.3}Y_{0.15}O_{3-{\delta}}$ | $BaCe_{0.55}Zr_{0.3}Y_{0.15}O_{3-{\delta}}$ | $Pr_2NiO_{4+{\delta}}$ single cell at $650^{\circ}C$. This result verifies that the $K_2NiF_{4+{\delta}}-type$ cathode shows good chemical compatibility which, in turn, will make it a potent candidate as a PCFC cathode.

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참고문헌

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  2. Ruddlesden-Popper perovskites in electrocatalysis vol.7, pp.10, 2018, https://doi.org/10.1039/d0mh00477d
  3. Perspectives on Cathodes for Protonic Ceramic Fuel Cells vol.11, pp.12, 2018, https://doi.org/10.3390/app11125363
  4. A review on cathode materials for conventional and proton-conducting solid oxide fuel cells vol.894, pp.None, 2018, https://doi.org/10.1016/j.jallcom.2021.162458