DOI QR코드

DOI QR Code

Numerical study on the design of urea decomposition chamber in LP SCR system

  • Um, Hyung Sik (Energy Technology Research Institute, Hyundai Heavy Industries Co, Ltd.) ;
  • Kim, Daehee (Energy Technology Research Institute, Hyundai Heavy Industries Co, Ltd.) ;
  • Kim, Keon Ho (Marine Machinery Design & Engineering Dep't, Hyundai Heavy Industries Co, Ltd.)
  • Received : 2017.03.17
  • Accepted : 2018.06.13
  • Published : 2019.01.31

Abstract

In order to design efficient Urea Decomposition Chamber (UDC) for the Low Pressure (LP) Selective Catalytic Reduction (SCR) system, numerical simulations were conducted with respect to various design parameters. The design parameters examined in this simulation include the chamber diameter, inlet and outlet shape of chamber, and urea injection point. Reaction kinetics for the urea decomposition was proposed and validated with the experimental data in the range of $300{\sim}450^{\circ}C$. The effects of design parameters on the performance of UDC were evaluated by the calculated urea conversion and pressure drop. As a result, the local optimum design values were derived by the parametric study.

Keywords

References

  1. Birkhold, F., Meingast, U., Wassermann, P., Deutschmann, O., 2007. Modeling and simulation of the injection of urea-water-solution for automotive SCR DeNOx-systems. Appl. Catal. 70, 119-127. https://doi.org/10.1016/j.apcatb.2005.12.035
  2. Choi, C., Sung, Y., C, G.M., Kim, D.J., 2015. Numerical analysis of NOx reduction for compacr design in marine ures-SCR system. Int. J. Archit. Ocean Eng. 7, 1020-1033. https://doi.org/10.1515/ijnaoe-2015-0071
  3. Cooper, D.A., 2001. Exhaust emissions from high speed passenger ferries. Atmos. Environ. 35 (24), 4189-4200. https://doi.org/10.1016/S1352-2310(01)00192-3
  4. Kim, J.Y., Ryu, S.H., Ha, J.S., 2004. Numerical Prediction on the characteristics of spray-Induced mixing thermal decomposition of urea solution in SCR system. In: ASME 2004 Internal Combustion Engine Division Fall Technical Conference, Long Beach, CA, USA, 24-27 October, pp. 165-170.
  5. Koebel, M., Elsener, M., Kleemann, M., 2000. Urea-SCR: a promising technique to reduce $NO_X$ emissions from automotive diesel engines. Catal. Today 59 (3), 335-345. https://doi.org/10.1016/S0920-5861(00)00299-6
  6. Magnusson, M., Fridell, E., Ingelsten, H.H., 2012. The influence of sulfur dioxide and water on the performance of a marine SCR catalyst. Appl. Catal. B Environ. 111-112, 20-26. https://doi.org/10.1016/j.apcatb.2011.09.010
  7. Mahalik, K., Sahu, J.N., Patwardhan, A.V., 2010. Kinetic Studies on hydrolysis of urea in a semi batch reactor at atmospheric pressure for safe use of ammonia in a power plant for flue gas conditioning. J. Hazard Mater. 175, 629-637. https://doi.org/10.1016/j.jhazmat.2009.10.053
  8. Park, T., Sung, Y., Kim, T., Lee, I., Choi, G., Kim, D., 2014. Effect of static mixer geometry on flow mixing and pressure drop in marine SCR applications. Int. J. Archit. Ocean Eng. 6, 27-38. https://doi.org/10.2478/IJNAOE-2013-0161
  9. Sahu, J.N., Mahalik, K., Patwardhan, A.V., Melkap, B.C., 2008. Equilibrium and kinetic studies on the hydrolysis of urea for ammonia generation in a semibatch reactor. Ind. Eng. Chem. Res. 47, 4689-4696. https://doi.org/10.1021/ie800481z
  10. Strom, H., Lundstrom, A., Andersson, B., 2009. Choice of urea-spray models in CFD simulations of urea-SCR systems. Chem. Eng. J. 150, 69-82. https://doi.org/10.1016/j.cej.2008.12.003
  11. Wu, B., Tang, G., Chen, X., Zhou, C.Q., Colella, C.P., Okosun, T., 2014. Optimization of an urea decomposition chamber using CFD and VR. Appl. Therm. Eng. 70, 827-837. https://doi.org/10.1016/j.applthermaleng.2014.05.044
  12. Yim, S.D., Kim, S.J., Baik, J.H., Nam, I.S., Mok, Y.S., Lee, J.W., Cho, B.K., Oh, S.H., 2004. Decomposition of urea into $NH_3$ for the SCR process. Ind. Eng. Chem. Res. 43 (16), 4856-4863. https://doi.org/10.1021/ie034052j

Cited by

  1. Numerical investigation of the high pressure selective catalytic reduction system impact on marine two-stroke diesel engines vol.13, 2019, https://doi.org/10.1016/j.ijnaoe.2021.09.003
  2. Optimization of the Urea Injection Angle and Direction: Maximizing the Uniformity Index of a Selective Catalytic Reduction System vol.14, pp.1, 2021, https://doi.org/10.3390/en14010157
  3. Numerical Analysis on Enhancing Spray Performance of SCR Mixer Device and Heat Transfer Performance Based on Field Synergy Principle vol.9, pp.5, 2021, https://doi.org/10.3390/pr9050786