Textile Coloration and Finishing (한국염색가공학회지)

The Korean Society of Dyers and Finishers (한국염색가공학회)
권호 표지
DOI QR코드

DOI QR Code

Eco-friendly Leather Dyeing Using Biomass Wastes(III): Imparting Functionality by Combination Dyeing with Marigold (Tagetes erecta L.) and Hinoki Cypress(Chamaecyparis obtusa) Leave Extracts

생물자원 폐기물을 활용한 친환경 가죽염색(III): 매리골드와 편백나무 잎 추출물의 복합염색에 의한 기능성 부여

  • Lee, Geonhee (Department of Clothing and Textiles/Human Ecology Research Institute, Chonnam National University) ;
  • Shin, Younsook (Department of Clothing and Textiles/Human Ecology Research Institute, Chonnam National University)
  • 이건희 (전남대학교 의류학과/생활과학연구소) ;
  • 신윤숙 (전남대학교 의류학과/생활과학연구소)
  • Received : 2019.02.18
  • Accepted : 2019.03.11
  • Published : 2019.03.27
Download PDF
⟨ Previous Next ⟩

Abstract

In this study, eco-friendly functional leather was developed by recycling wastes such as eel skin, marigold(Tagetas erecta l.), hinoki cypress(Chamaecyparis obtusa). The hot water extracts of marigold and hinoki cypress leaves were freeze-dried at $-80^{\circ}C$ to prepare colorant powder. The dyeing of eel leather with marigold was carried out to investigate the effects of dyeing conditions, mordanting on dye uptake, color, morphological change, and color fastness. Considering shrinkage of eel leather caused by dyeing, the optimum dyeing conditions were $60^{\circ}C$ of dyeing temperature and 60 min of dyeing time at 1:100 of bath ratio, and color of the dyed eel leather was Y to YR Munsell series. In order to prevent the degradation of leather from microbe, we conducted combination dyeing with marigold and hinoki cypress leave colorants. In this case, the combination dyed eel leathers showed excellent antimicrobial activity with above 99% bacterial reduction rate against S. aurieus and K. pneumoniae. It was confirmed that all of the dyed eel leathers were sufficient to meet the Korean Standard for color fastness of leather products. It can be applied practically for the development of eco-friendly functional leather by utilizing some useful active components extracted from plant resources and by recycling food wastes.

Keywords

OSGGBT_2019_v31n1_1_f0001.png 이미지

Figure 1. Chemical structure of (a) Lutein and (b) Zeaxanthin.

OSGGBT_2019_v31n1_1_f0002.png 이미지

Figure 2. Chemical structure of (a) Quercetin, (b) Taxifolin, and (c) Kaempferol.

OSGGBT_2019_v31n1_1_f0003.png 이미지

Figure 3. Dyeing process.

OSGGBT_2019_v31n1_1_f0004.png 이미지

Figure 4. K/S value of eel leather dyed with marigold according to dyeing temperature.

OSGGBT_2019_v31n1_1_f0005.png 이미지

Figure 5. K/S value of eel leather dyed with marigold according to dyeing time.

OSGGBT_2019_v31n1_1_f0006.png 이미지

Figure 6. K/S value of eel leather dyed with marigold according to colorant concentration.

OSGGBT_2019_v31n1_1_f0007.png 이미지

Figure 7. K/S value of 1-Bath combination dyed eel leather.

OSGGBT_2019_v31n1_1_f0008.png 이미지

Figure 8. K/S value of 2-Bath combination dyed eel leather.

Table 1. Characteristic of eel leather

OSGGBT_2019_v31n1_1_t0001.png 이미지

Table 2. Shrinkage ratio of eel leather by dyeing conditions

OSGGBT_2019_v31n1_1_t0002.png 이미지

Table 3. SEM(×100) image of eel leather dyed with marigold according to dyeing temperature(dyeing time:30min, colorant concentration: 5% owf)

OSGGBT_2019_v31n1_1_t0003.png 이미지

Table 4. SEM(×100) image of eel leather dyed with marigold according to dyeing time(dyeing temperature: 60℃, colorant concentration: 5% owf)

OSGGBT_2019_v31n1_1_t0005.png 이미지

Table 5. SEM(×100) image of eel leather dyed with marigold according to colorant concentration(dyeing temperature:60℃, dyeing time: 60min)

OSGGBT_2019_v31n1_1_t0006.png 이미지

Table 6. The color characteristic of pre and post-mordanted eel leather dyed with marigold

OSGGBT_2019_v31n1_1_t0007.png 이미지

Table 7. The color characteristics of combination dyed eel leather

OSGGBT_2019_v31n1_1_t0008.png 이미지

Table 8. Color fastness of dyed eel leather

OSGGBT_2019_v31n1_1_t0009.png 이미지

Table 9. Antimicrobial activity of dyed eel leather

OSGGBT_2019_v31n1_1_t0010.png 이미지

References

  1. http://www.sbiz.or.kr/neb/nebidea/1190796_1175.jsp, 2018.11.23.
  2. https://brunch.co.kr/@light903, 2018.11.05.
  3. J. T. Kim, B. Y. Son, J. S. Lee, S. B. Baek, S. L. Kim, M.J. Kim, G. H.Jung, and Y. U. Kwon, Natural Dyeing Fabrics with Leaf and Stem of Purple Corn, Korean J. of Crop Science, 58(2), 113(2013). https://doi.org/10.7740/kjcs.2013.58.2.113
  4. H. S. Lee and E. Y. Kang, Dyeing of Cotton Fabrics using Residual Parts of Cultivated Pteridium aquilinum, Textile Coloration and Finishing, 26(1), 53(2014). https://doi.org/10.5764/TCF.2014.26.1.53
  5. H. A. Yang and Y. M. Park, OptimumDyeingCondition of Cotton by Fermented Grape By-products with Degraded Protein Mordant, Textile Coloration and Finishing, 27(3), 202(2015). https://doi.org/10.5764/TCF.2015.27.3.202
  6. B. G. Heo, D. H. Lee,J. K. Suh, and S. B. Lee, A Study on the Use of Roadside container gardens in Kwangju Chonnam Area, J. Agric. Sci. Res., 7, 61(1993).
  7. K. Zitterl-Eglseer, S. Sosa, S. Jurenitsch, J. Schubert-Zsilavecz, M. Loggia, R. Tubaro, A. Bertoldi, and M. Franz, Anti-oedematous Activities of the Main Triterpendiol Esters of Marigold(Calendula officinalis L.), J. Ethnopharmacol., 57, 139(1997). https://doi.org/10.1016/S0378-8741(97)00061-5
  8. http://blog.daum.net/goldenboy1960/141, 2018.11.26.
  9. K. S. Kim and D. W.Jeon, Effect of Absorbed MetalIon Concentration by After-treated Mordanting on theColor and Fastnessin Human Hair and Wool Fiber Dyed with African Marigold Petals Extract, J. of Fashion Business, 10(5), 45(2006).
  10. K. S. Kim and D. W.Jeon, Effect of Dyeing Bath, Mordanting and Chitosan Treatment on the Dyeing of Natural Proteinic Fabrics Using African Marigold(Tagetes erecta L.) Petals Extract, J. of Fashion Business, 11(2), 92(2007).
  11. M. J. Park, W. S. Choi, B. C. Min, H. Y. Kim, H. Y. Kang, and I. G.Choi, Antioxidant Activities of Essential Oils from Chamaecyparis obtusa, J. of theKorean Wood Science and Technology, 36(6), 159(2008).
  12. S. E. Jo and D. H. Yi, Antioxidant and Anti-inflammatory Activity of Leaves Extracts of Chamaecyparis Obtusa, J. of the Korean Society of Cosmetology, 17(5), 970(2011).
  13. D. S. Lee, M. S. Lim, S. S. Kwan, S. Y. Kim, and S. N. Park, Antioxidative Activity andComponential Analysis of Chamaecyparis obtusa Leaf Extract, Applied Chemistry for Engineering, 23(1), 93(2012).
  14. S. C. Cheng, W. H. Li, Y. C. Shi, P. L. Yen, H. Y. Lin, V. H.C. Liao, and S. T.Chang, Antioxidant Activity and Delayed Aging Effects of Hot Water Extract from Chamaecyparis obtusa var. formosana Leaves, J. of Agricultural and Food Chemistry, 62(18), 4159(2014). https://doi.org/10.1021/jf500842v
  15. J. H. Kim, S. O. Lee, K. B. Do, and W. D. Ji, Analysis of the Component and Immunological Efficacy of Chamaecyparis obtusa Leaf Extract, Original Article Korean J. Clin. Lab. Sci., 50(1), 37(2018). https://doi.org/10.15324/kjcls.2018.50.1.37
  16. S. K. Bai, Natural Dyeability of Cow Leather Dyeing with Turmeric powder, J. of Fashion Business, 15(4), 182(2011). https://doi.org/10.12940/JFB.2011.15.4.182
  17. S. K. Bai, Mordanting Effect of Chestnut's Inner Skin on the Cow Leather Dyed with Turmeric powder, J. of Fashion Business, 16(4), 100(2012). https://doi.org/10.12940/jfb.2012.16.4.100
  18. S. K. Bai, Dyeing Conditions and Mordant Effects on the Cow Leather Dyed with Lac Powder, J. of Fashion Business, 17(4), 140(2013). https://doi.org/10.12940/jfb.2013.17.4.140
  19. S. Y. Kim, Natural Dyeing of Cow Leather with Cochineal, The Research J. of the Costume Culture, 24(6), 817(2016). https://doi.org/10.29049/rjcc.2016.24.6.817
  20. S. Y. Kim, Nature Dyeing of Sheep Leather with Amur Cork Tree, J. of Fashion Business, 20(5), 76(2016). https://doi.org/10.12940/jfb.2016.20.5.76
  21. http://news.chosun.com/site/data/html_dir/2017/09/29/2017092902443.html, 2018.11.23.
  22. W. J. Kim, S. B. Shin, B. W. Min, and J. S. Heo, Pesticide, Environment Chemistry : Study on the Antibiotic Effect of Casual Shoe Usage Leather, J. Korean Soc. Agri. Chem. Biotechno., 44(3), 257(2010).
  23. B. J. Rigby and J. D. Spikes, Hydroxyproline and the Shrinkage Temperature of Collagen, Nature, 187, 150 (1960). https://doi.org/10.1038/187150a0
  24. W. J. Kim, "Leather & Enviroment", Adbooks, Seoul, pp.65-66, 2006.
  25. Y. Yeo, D. I. Yoo, and Y. Shin, Eco-friendly Leather Dyeing using Biomass Wastes (I): Natural Dyeing of Eel Skin using Onion Peels, Textile Coloration and Finishing, 30(2), 141(2018). https://doi.org/10.5764/TCF.2018.30.2.141
  26. B. G. Heo, H. G.Jang, S. H. Kim, W. N. Hou,J. Y.Cho, and Y. J. Park, Effects of Dyeing Conditions of Natural Colorants from Disused Marigold Plants on Dyeability of Silk Fabrics, Korean J. of Horticultural Science and Technology, 22(3), 364(2004).
  27. Y. J. Park, S. P. Lee, H. J. Kim, H. G. Jang, J. R. Choi, and B. G. Heo, Effect of Marigold Extracts and Powdered Colorant on the Dyeability and Antifungal Activity of Silk and Cotton Fabrics, Korean J. Community Living Science, 17(4), 39(2006).
  28. G.J. An, "The Science of Dyeing", Gyeonchunsa, Seoul, pp.197-200, 2000.
  29. M. W. Kim, "Leather Industry Chemistry", Sunjinprinting, Seoul, pp.60-61, 2008.