The propagation rates ($U_{edge}$) of various premixed edge-flames were measured as a function of global strain rate (${ \sigma}$), mixture strength, and Lewis number (Le). Using a counterflow slot-jet burner with electrical heaters at each end, both advancing (positive $U_{edge}$) and retreating (negative $U_{edge}$) edges can be studied as they propagate along the long dimension of the burner. Preliminary results are presented for single and twin premixed hydrocarbon edge-flames in terms of the effects on $U_{edge}$. A low-${\sigma}$ extinction limit has been discovered for all mixtures tested but further analysis is necessary for full characterization since sufficiently $high-{\sigma}$ leads to an apparent stability limit. Propagation rates clearly show a strong dependence on Le. Future work will focus on completing the premixed hydrocarbon edge-flame analysis and include investigations into non-premixed edge-flames and edge-flames composed of fuels such as hydrogen ($H_2$) with significantly lower Le.

Radiant burners are applicable to drying, preheating and curing in materials manufacturing processes. High radiation efficiency is one of the most important performance criteria for these burners. The wide variation in reported radiation efficiencies are partly due to the differences in the measurement techniques. In the present work, water cooled radiant heat flux meter was used to measure radiant heat flux from a metal fiber mat burner. Non-contact type thermometer was also utilized to measure the surface temperature of the burner. Combustion gas was measured by gas analyzers. According to the thermal loads and stoichiometric ratios, radiant heat transfer ratio and combustion performance were discussed here in.

Energy efficient and low pollution combustion systems the use gaseous fuels have been in great demand in recent year. Radiant burner in many different forms are emerging as very desirable combustion systems for same reason. Porous radiant burners are used in drying, preheating and curing, and in other type of materials processing and manufacturing processes. However, little knowledge is available about the operating characteristics and the structure of flames in porous ceramic fiber radiant burners. The objective of the present work is to investigate the global performance characteristics of the ceramic fiber burner. A detailed study which includes the spectral intensity, gas temperature, radiation efficiency and global pollutant emissions. Another objective is to study the flame structure of the ceramic fiber burner by measuring the local gas temperature. The results indicate that ceramic fiber burner do offer a 19-44% gain in radiant efficiency. The ceramic fiber burner exhibit significant spectral intensity peaks in the band at $2.0-2.5{\mu}m$. The local temperature distribution inside the mat and near the mat surface as a function of the equivalence ratio can be reasonably interpreted by the relation of the heat balance in the mat and movement of the reaction zone. Nox emission from ceramic fiber burner is less than 25ppm throughout the operating range.

Flickering behaviors of lean premixed flame of propane/air and methane/air flame anchored by a pilot flame in a tube were investigated. Unsteady behaviors of the flame were monitored by a high speed ICCD camera and the flickering frequency was defined as the number of flame curvatures passing a fixed spatial point in a second. Unlike previous studies in which flames are in open condition so that the flickering mechanism is an unstable interaction of hot buoyant products with the ambient air, flames in this study are surrounded by a tube which means they are not open to ambient air, so that there is no interaction between hot buoyant products and ambient air. Despite the fact, there exists flickering phenomena and the flickering frequency ranges from 10 Hz to 50 Hz which is wider compared to previous studies. We relate the flickering mechanism to flame-generated vorticity and analytic solution for locally approximated flow is used. As a result, the relationship between flickering wavelength and dimensionless vorticity is acquired and the cause of higher range of flickering frequency is explained.

A premixed flame propagating in a tube suffers strong variation in its shape and structure depending on boundary conditions. The effects of thermal boundary conditions and flow fields on flame propagation are numerically investigated. Navier-Stokes equations and species equations are solved with a one-step irreversible global reaction model of methane-air mixture. Finite volume method using an adaptive grid method is applied to investigate the flame structure. In the case of an adiabatic wall, friction force on the wall significantly affected the flame structure while in the case of an isothermal wall, local quenching near the wall dominated flame shapes and propagation. In both cases, variations of flow fields occurred not only in the near field of the flame but also within the flame itself, which affected propagation velocities. This study provides an overview of the characteristics of flames in small tubes at a steady state.

Analysis of the internal state of the blast furnace is needed to predict and control the operating condition. Especially, it is important to develop modeling of blast furnace for predicting cohesive zone because shape of cohesive zone influences overall operating condition of blast furnace such as gas flow, chemical reactions and temperature. because many previous blast furnace models assumed cohesive zone to be fixed, they can't evaluate change of cohesive zone shape by operation condition such as PCR, blast condition, and production rate. In this study, an axi-symmetric 2-dimensional steady state model is proposed to simulate blast furnace process. In this model, cohesive zone is changed by solid temperature range, FVM is used for numerical simulation. To find location of cohesive zone whole calculation procedure is iterated Until cohesive zone is converged. Through this approach, shape of cohesive zone, velocity, composition and temperature within the furnace are predicted by model.

The present study conducted a numerical modeling on the diesel SCR (selective catalytic reduction) system using ammonia as a reductant over vanadium-based catalysts $(V_2O_5-WO_3/TiO_2)$. Transient modeling for ammonia adsorption/desorption on the catalyst surface was firstly carried out, and then the SCR reaction was modeled considering for it. In the current catalytic reaction model, we extended the pure chemical kinetic model based on laboratory-scale powdered-phase catalyst experiments to the chemico-physical one applicable to realistic commercial SCR reactors. To simulate multi-dimensional heat and mass transfer phenomena, the SCR reactor was modeled in two dimensional, axisymmetric domain using porous medium approach. Also, since diesel engines operate in transient mode, the present study employed an unsteady model. In addition, throughout simulations using the developed code, effects of space velocity on the DeNOx performance were investigated.

A two-step fuel-rich/fuel-lean catalytic combustion seems to be one of the most effective methods to control simultaneously the NO generation and the hydrocarbon (HC) conversion from fuel-bound nitrogen. By controlling equivalent air ratio for maintaining fuel-rich and fuel-lean condition over each catalytic layer, space velocity, inlet temperature, and catalyst component, the HCand ammonia conversion efficiency higher than 95% could be achieved, with ammonia conversion to NO remaining below 5%. The experimental results wouldbe applied to the combustion of land fill gas and to gasified refuse-derived fuels as a method of minimizing NO generation.

Effects of oxidizer inlet velocity on NO emission characteristics of 0.2MW oxy-fuel combustor have been experimentally investigated. The NO formation process in the oxy-fuel combustion is extremely sensitive even for the small fraction of nitrogen in oxidizer. By increasing the oxidizer velocity, flame length is reduced due to the enhanced turbulent mixing. The increased oxidizer velocity also results in the decreased flame temperature through the elevated entrainment rate of the recirculated product and the corresponding NO emission is drastically decreased. Experimental results clearly indicate that the entrained product gases play a crucial role to decrease the temperature at the flame zone and the post flame zone where the thermal NO is mainly formed.

An Experimental study was conducted on $CO_2$ recycle combustion heating system using pure oxygen instead of conventional air as an oxidant, which is thereby producing a flue gas of mostly $CO_2$ and water vapor($H_2O$) and resulting in higher $CO_2$ concentration. The advantages of the system are not only the ability to control high temperatures characteristic of oxygen combustion with recycling $CO_2$. but also the possibility to reduce NOx emission in the flue gas. A small scale industrial reheating furnace simulator and specially designed variable flame burner were used to characterize the $CO_2$ recycle oxy-fuel combustion, such as the variations of furnace pressure, temperature and composition in the flue gas during recycle. It was found that $CO_2$ concentration in the flue gas was about 80% without $CO_2$ recycle, but increased to $90{\sim}95%$ with $CO_2$ recycle. The furnace temperature and pressure was decreased due to recycle and the NOx emission was also reduced to maintain under 100ppm.

Disposal of highly toxic wastes like polychlorinated biphenyls (PCBs) is very difficult. These substances create a growing mountain of problematic waste that has to be disposed properly. Conventional technologies that are based on common burning(rotary kiln, ${\sim}1100^{\circ}C$) and plasma technology(${\sim}10000^{\circ}C$) do not satisfy important conditions. for example, complete combustion of the toxic waste and the price of waste disposal. The combustor like a rocket engine is operated at relatively high pressure(${\sim}15$ bar) and relatively high temperature(>$3000^{\circ}C$) that are ideal for the complete destruction of extremely toxic substances. In this study, test compound($_o-DCB$) was dissolved in kerosine with a concentration of 10%. Pure gas oxygen was used as an oxidant. Analysis showed that the destruction efficiency achieved for ${o}-DCB$ was 99.9999% or better. The results show that a combustor based on liquid propllant rocket technology is a validated tool for the disposal of highly toxic waste, and a good alternative technology when applied to the destruction of extremely toxic wastes.

In this study, to increase the mixing between flue gas and reducing agent, new shapes of $NH_3$ ejection nozzles are designed and experimentally and numerically tested. The nozzles have six holes perpendicular to the ambient flue gas flow and the tilting angle between direction of ambient flow and the hole axis is varied. To evaluate the mixing efficiency of the proposed nozzles, numerical and experimental tests are applied to several flow conditions comparing with single hole nozzle, which is commonly used in conventional SCR process. From the results the nozzle with tilted multi-holes has the large region of high turbulent intensity compared with conventional single hole nozzle. This is originated from the high vorticity near the upstream of the jet flow issuing from the hole. The high turbulent intensity and vorticity magnitude lead to enhanced mixing between flue gas and reducing agent. Hence, the most suitable moral ratio between NOx and reducing agent for the catalytic reaction can be obtained on behalf of the intensified scalar mixing within shorter physical mixing length.

This study has numerically modelled the combustion processes of the turbulent swirling premixed lifted flames in the low-swirl burner (LSB). In these turbulent swirling premixed flames, the four tangentially-injected air jets induce the turbulent swirling flow which plays the crucial role to stabilize the turbulent lifted flame. In the present approach, the turbulence-chemistry interaction is represented by the level-set based flamelet model. Two-dimensional and three-dimensional computations are made for the various swirl numbers and nozzle length. In terms of the centerline velocity profiles and flame liftoff heights, numerical results are compared with experimental data The three-dimensional approach yields the much better conformity with agreements with measurements without any analytic assumptions on the inlet swirl profiles, compared to the two-dimensional approach. Numerical clearly results indicate that the present level-set based flamelet approach has realistically simulated the structure and stabilization mechanism of the turbulent swirling stoichiometric and lean-premixed lifted flames in the low-swirl burner.

In the present paper, the effects of combustion instability on flow structure and flame dynamic with the configurations of burner exit in a model gas turbine combustor are investigated using large eddy simulation(LES). A G-equation flamelet model is employed to simulate the unsteady flame behavior. As a result of mean flow field, the change of divergent half angle(${\alpha}$) at burner exit results in variations in the size and shape of the central toroidal recirculation(CTRZ) as well as flame length by changing corner recirculation zone(CRZ). The case of ${\alpha}=45^{\circ}$ show smaller size and upstream location of CTRZ than that of $90^{\circ}$ and $30^{\circ}$ by the development of higher swirl velocity. The flame length in the case of ${\alpha}=45^{\circ}$ is the most shortest, while that in the case of ${\alpha}=30^{\circ}$ is the longest by the decrease of effective reactive area with the absence of CRZ. Through the analysis of pressure fluctuation, it is identified that the case of ${\alpha}=45^{\circ}$ shows the most largest damping effect of pressure oscillation in all configurations and brings in the noise reduction of 2.97dB, comparing with that of ${\alpha}=30^{\circ}$ having the largest pressure oscillation. These reasons are discussed in detail through the analysis of unsteady phenomena about recirculation zone and flame surface. Finally the effects of flame-acoustic interaction are evaluated using local Rayleigh parameter.

Many previous works have been performed to provide correlations of flame length, theoretically and experimentally. Most of these results studied were conducted in vertical turbulent flame with no coaxial air condition. The present study analyzes the flame length scaling with coaxial air. In turbulent hydrogen non-premixed jet flames with coaxial air, flame length scaling theoretically proposed so far has been related with the concept of a far-field equivalent source. At high coaxial air to fuel velocity ratio, $U_A/U_F$, however, this scaling theory has some difference with experimental flame length data. This difference is understood to be due to the fact that the theory is based on far-field notion, while the effect of coaxial air on jet flame occurs in the region near the nozzle exit. Therefore, we define effective jet density $P_{eff}$ involving the concept of near-field so that effective jet diameter can be extended to the near-field region. In this condition, we modify the correlation and compare with experimental data.

The fully coupled conditional moment closure(CMC) model has been developed to realistically simulate the structure of complex turbulent nonpremixed syngas flame, in which the flame structure could be considerablyl influenced by the turbulence, transport history, and heat transfer as well. In order to correctly account for the transport effect, the CMC transport equations fully coupled with the flow and mixing fields are numerically solved. The present CMC approach has successfully demonstrated the capability to realistically predict the detailed structure and the overall combustion characteristics. The numerical results obtained in this study clearly reveal the importance of the convective and radiative heat transfer in the precise structure and NOx emission of the present confined combustor with a cooling wall.

It has become inevitable to search for alternative fuels due to severe energy crisis these days. Use of alternative fuels, which are typically of lower quality, tends to increase environmental pollution, including formation of nitrogen oxides (NOx). In this paper performance of vacuum residue has been investigated experimentally as well as numerically in typical operating conditions of a furnace. Heat release reaction is modeled as sequential steps of devolatilization, simplified gas phase reaction and char oxidation as that for pulverized coal. Thermal and fuel NOx are predicted by conditional estimation of elementary reaction rates and are compared against measured experimental data. On the overall reasonable agreement is achieved for spatial distributions of major species, temperature and NOx for all test cases.

A characterization of turbulent reacting flows has proved difficult owing to the complex interaction between turbulence, mixing, and combustion chemistry. There are many types of time scales in turbulent flame which can determine flame structure. This counter jet type premixed burner produces high intensity turbulence. The goal is to gain better insights into the flame structures at high turbulence. 6 propane/air flames gave been studied with high velocity fluctuation in bundle type nozzle and in one hole type nozzle. By measuring velocity fluctuation, turbulent intensity and integral length scale are obtained. And sets of OH LIF images were processed to see flame structure of the mean flame curvatures and flame lengths for comparison with turbulence intensity and turbulent length scales. The results show that the decrease in nozzle size generates smaller flow eddy and mean curvatures of the flame fronts, and a decrease in Damkohler number estimated from flow time scale measurement.

The effect of electric fields on flame speed has been investigated experimentally by observing propagating premixed flames in a tube for methane/air mixtures. The flame speeds were measured in both the normal and micro gravity conditions to substantiate the measurements. The results show that the flame speeds were enhanced by both the AC and DC electric fields, as the flame approached to the high voltage electrode located on the one end of the tube. The enhancement of flame speed was proportional to the square root of the electric field intensity, defined as the voltage applied divided by the distance of flame from the high voltage electrode, when the electric field intensity is sufficiently large. When the electric field intensity was low, there existed critical intensities, below which the electric fields did not influence the flame speed. This critical electric field intensity correlated well with the flame speed.

Characteristics of a plasma reactor for partial oxidation of methane, especially focused on the role and effectiveness of plasma chemistry, is investigated. Partial oxidation of methane is investigated using a rotating arc which is a three dimensional version of a typical glidingarc. The rotating arc has both the characteristics of equilibrium and non-equilibrium plasma. Non-equilibrium characteristics of the rotating gliding arc can be increased by rotating an elongated arc string attached at both the tip of inner electrode and the edge of outer electrode. In this way, plasma chemistry can be enhanced and hydrogen selectivity can reach almost 100% that is much higher than thermal equilibrium condition. As a result, the present study enables the strategic approach of the plasma reforming process by means of appropriate reactor design to maximize plasma effect and resulting in maximized reaction efficiency.

Structure of edge flame established in a mixing layer, formed between two uniformly flowing pure $CH_4$ and pure $O_2$ streams, is numerically investigated by employing a detailed methane-oxidation mechanism. The numerical results exhibited the most outstanding distinction of using pure oxygen in the fuel-rich premixed-flame front, through which the carbon-containing compound is found to leak mainly in the form of CO instead of HC compounds, contrary to the rich $CH_4-air$ premixed flames in which $CH_4$ as well as $C_2H_m$ leakage can occur. Moreover, while passing through the rich premixed flame, a major route for CO production, in addition to the direct $CH_4$ decomposition, is found to be $C_2H_m$ compound formation followed by their decomposition into CO. Beyond the rich premixed flame front, CO is further oxidized into $CO_2$ in a broad diffusion-flame-like reaction zone located around moderately fuel-rich side of the stoichiometric mixture by the OH radical from the fuel-lean premixed-flame front. Since the secondary CO production through $C_2H_m$ decomposition has a relatively strong reaction intensity, an additional heat-release branch appears and the resulting heat-release profile can no longer be seen as a tribrachial structure.

A new technique utilizing LII signal for the measurement of flow velocities of laminar diffusion flames has been investigated. Soot particles in ethylene diffusion flames are heated by a modulated Ar-ion laser beam. LII signals and their phase angles are measured using a lock-in amplifier at the different flame heights and the axial flow velocity are obtained from the measured phase angle delay. The measured velocities are similar to those from LDV measurements under the same operating conditions. The effects of laser power, LII signal wavelength, and modulation frequency are not sensitive to the velocity measurement. However, the choice of an optical chopper blade type could affect the measurement result. The use of a 6/5 chopper blade showed the better result that is possibly due to the square shape of modulated laser beam. This study successfully demonstrated that axial flow velocities of laminar diffusion flames can be measured by a new technique utilizing LII signal, which does not need particle seeding unlikely to LDV or PIV techniques.

The previous models for thermal behavior in the melting furnace were deterministic, composed of such a form that if the initial input conditions are determined, the results would have been come out by using the basic heat equilibrium equations. But making the experiment by trusting the analysis results, the melted slag is fortuitously set often, because temperature variation of the melted slag in the reaction process is not point function but path function. So in this study, a transient model was developed and verified by comparing with the experimental results.

A novel pyrolysis-melting incineration system of reduced scale (30 kg/hr) is and constructed in Korea Institute of Industrial Technology. The incineration process is composed of three parts: pyrolysis, gas combustion and ash melting processes. For each unit process, experimental and numerical approaches including reduced-scale cold/hot flow tests have been conducted to find optimal design and operating conditions. This paper presents major results of these approaches with brief descriptions on the pilot-scale incinerator (200 kg/hr) under construction and future research works.

Operation parameters for large scale industrial facility such as iron making plant are carefully selected through elaborate tests and monitoring rather than through a mathematical modeling. One of the recent progresses for better energy utilization in iron ore sintering process is the distribution pattern of fuel inside a macro particle which is formed with fines of iron ore, coke and limestone. Results of model tests which have been used as a basis for the improved operation in the field are introduced and a theoretical modeling study is presented to supplement the experiment-based approach with fundamental arguments of physical modeling, which enables predictive computation beyond the limited region of tests and adjustment. A single fuel particle model along with one-dimensional bed combustion model of solid particles are utilized, and thermal processes of combustion and heat transfer are found to be dominant consideration in the discussions of productivity and energy utilization in the sintering process.

Experiments were performed to investigate the melting characteristics of pellet fuel made of LDPE and PP for a waste plastic firing boiler. Pellet fuel in a burner goes through conduction, convection and radiation transferred from flame in a furnace, and complex thermo/chemical processes. To figure out effects of ambient temperature and size of pellet on melting time pellets with a diameter from 5 mm to 40 mm were made to contact high temperature flue gas generated by a LNG firing pilot burner. Though melting processes of plastics include complicated heat transfer in a burner, parameters are limited to flue gas temperature and size for the simplicity in this study. From the results, melting times of LDPE and PP with a diameter of 5mm are 63 and 62 secs respectively at 600 $^{\circ}C$ while 677 and 583 sees respectively for a diameter of 40 mm. At $900^{\circ}C$, melting times of LDPE and PP with a diameter of 5mm are 21 and 24 sees respectively while 408 and 337 secs respectively for a diameter of 40 mm. It is found that melting time of LDPE is longer than that of PP, and melting times of both in general increase with diameter of pellets. It is thought melting is dependent mostly on melting temperature of plastic. It is expected melting times obtained from the study might be taken into account in designing a pellet firing burner for a boiler

The model cavity scramjet engine experiments are carried out using T3 free-piston shock tunnel. Upstream hydrogen fuel is injected before the cavity with different injection pressure. OH planar laser-induced fluorescence is used to investigate the combustion zone and piezoelectric pressure transducers are used to define the pressure rise due to the combustion. Main combustion region is a mixing layer which is between air and fuel. Also high OH fluorescence signal is appeared in the shear layer above the cavity in high equivalence ratio. From the OH signal in the cavity, this fuel injection system can be a role as a flame- holder.

Three-dimensional numerical study was carried out for the investigation of the detonation wave structures propagating in tubes. Fluid dynamics equations and conservation equation of reaction progress variable were analyzed by a MUSCL-type TVD scheme and four stage Runge-Kutta time integration. Chemical reaction was modeled by using a simplified one-step irreversible kinetics model. The variable gas properties between unburned and burned states were considered by using variable specific heat ratio formulation. The unsteady computational results in three-dimension show the detailed mechanisms of rectangular and diagonal mode of detonation wave instabilities resulting same cell length but different cell width in smoked-foil record. The results for the small reaction constant shows the spinning mode of three-dimensional detonation wave dynamics, which was rarely observed in the previous numerical simulation of the detonation waves.

Recent advances in energetic materials modeling and high-resolution hydrocode simulation enable enhanced computational analysis of bio-medical treatments that utilize high-pressure shock waves. Of particular interest is in designing devices that use such technology in medical treatments. For example, the generated micro shock waves with peak pressure on orders of 10 GPa can be used for treatments such as kidney stone removal, trans-dermal micro-particle delivery. and cancer cell removal. In this work, we present a new computational methodology for applying the high explosive dynamics to bio-medical treatments by making use of high pressure shock physics and multi-material wave interactions. The preliminary calculations conducted by the in-house code, GIBBS2D, captures various features that are observed from the actual experiments under the similar test conditions. We expect to gain novel insights in applying explosive shock wave physics to the bio-medical science involving drug injection. Our forthcoming papers will illustrate the quantitative comparison of the modeled results against the experimental data.

Due to the high density and heating value, liquid fuel is attractive for ramjet propulsion system. Liquid fuel requires time to evaporation and mix with incoming air before ignition; insufficient evaporation and mixing result in low combustion efficiency and instability. So the numerical studies are conducted to investigate the spray and combustion characteristics of a liquid-fueled dump type Ramjet combustor. The governing equations are solved by means of a finite-volume using time derivative preconditioning method for chemical reacting flow. The liquid phase is treated by solving Lagrangian equations of motion and transport for the life histories of a statistically significant sample of individual droplets.