• Title/Summary/Keyword: Critical mixing rate

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Shear Thickening Behavior of Fumed Silica Suspension in Polyethylene Glycol (폴리에틸렌 글리콜 내에서의 흄드 실리카 현탁액의 전단농화 거동연구)

  • Park, Hye-Su;Cho, Bong-Sang;Yoo, Eui-Sang;Ahn, Jae-Beom;Noh, Si-Tae
    • Applied Chemistry for Engineering
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    • v.22 no.4
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    • pp.384-389
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    • 2011
  • We made suspension of fumed silica in polyethylene glycol (PEG), studied rheological behavior as functions of contents of silica, dispersion condition, PEG molecular weight, temperature and contents of humidity. Rheological behavior of suspension was determined critical shear rate and rise of viscosity using rheometer AR2000. Suspension were PEGs of molecular weight 200, 400, and 600. Fumed silica suspensions of which silica contents are 5, 7, 9, 13, and 18% were prepared by normal mixing, homogenization and bead milling process. We observed their rheological behaviors at 10, 20, 30, and $40^{\circ}C$. As the PEG molecular weight and contents of silica increase, the critical shear rate was lowered. As the temperature increased, the critical shear rate was increased. Humidity contents of dispersion don't influence on the critical shear rate, but dispersion processes greatly affect the critical shear rate. The critical shear rate of suspensions prepared by the mixing process was the lowest, and that of suspensions prepared by the bead milling process was the highest. The rise in the shear viscosity of suspensions prepared by the mixing process is higher than that of suspensions prepared by the bead milling process. This was dependent on the dispersion condition of silica particle by dispersion process.

A Study on Mixing Enhancement by Rotating and Oscillating Stirrers in the Micro Channel (미소채널 내 회전교반기와 진동교반기에 의한 혼합향상의 연구)

  • An Sang-Joon;Kim Yong-Dae;Maeng Joo-Sung
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.30 no.5 s.248
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    • pp.430-437
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    • 2006
  • The mixing effect is studied by comparing rotating and oscillating stirrers in the micro channel. The cases of Re=10 to 80 with various stirring speeds are considered to analysis the effect of Re and stirrer speed for the mixing. Under Re=20, the oscillating stirrer represents better mixing rate than the rotating stirrer up to the critical stirrer speed which has a maximum efficiency. Over Re=30, the results of oscillating and rotating stirrer show that the faster the stirrer speed, the higher the mixing effect within the concerned stirrer speed range and the oscillating stirrer keeps the higher mixing rate. It was found that the mixing effect is a function which has an optimum of the Reynolds number and the stirrer speed. The D2Q9 Lattice Boltzmann Method is used due to the merits of calculation for the unsteady flow with moving boundary.

3D Printing-Based Ultrafast Mixing and Injecting Systems for Time-Resolved Serial Femtosecond Crystallography (시간 분해 직렬 펨토초 결정학을 위한 3차원 프린팅 기반의 초고속 믹싱 및 인젝팅 시스템)

  • Ji, Inseo;Kang, Jeon-Woong;Kim, Taeyung;Kang, Min Seo;Kwon, Sun Beom;Hong, Jiwoo
    • Korean Chemical Engineering Research
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    • v.60 no.2
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    • pp.300-307
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    • 2022
  • Time-resolved serial femtosecond crystallography (TR-SFX) is a powerful technique for determining temporal variations in the structural properties of biomacromolecules on ultra-short time scales without causing structure damage by employing femtosecond X-ray laser pulses generated by an X-ray free electron laser (XFEL). The mixing rate of reactants and biomolecule samples, as well as the hit rate between crystal samples and x-ray pulses, are critical factors determining TR-SFX performance, such as accurate image acquisition and efficient sample consumption. We here develop two distinct sample delivery systems that enable ultra-fast mixing and on-demand droplet injecting via pneumatic application with a square pulse signal. The first strategy relies on inertial mixing, which is caused by the high-speed collision and subsequent coalescence of droplets ejected through a double nozzle, while the second relies on on-demand pneumatic jetting embedded with a 3D-printed micromixer. First, the colliding behaviors of the droplets ejected through the double nozzle, as well as the inertial mixing within the coalesced droplets, are investigated experimentally and numerically. The mixing performance of the pneumatic jetting system with an integrated micromixer is then evaluated by using similar approaches. The sample delivery system devised in this work is very valuable for three-dimensional biomolecular structure analysis, which is critical for elucidating the mechanisms by which certain proteins cause disease, as well as searching for antibody drugs and new drug candidates.

Improvement of the Blasting Productivity by Optimizing the Abrasive-to-Air Mixing Ratio (Grit와 Air의 혼합비 최적화를 통한 블라스팅 효율 향상)

  • Bae, Han-Jin;Baek, Jae-Jin;Kim, Eul-Hyun;Chung, Mong-Ku;Shin, Chil-Seok;Baek, Kwang-Ki
    • Proceedings of the KSME Conference
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    • 2004.11a
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    • pp.1436-1441
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    • 2004
  • Achieving the maximum blasting efficiency with minimum abrasive consumption is a critical concern in surface preparation stage of shipbuilding and offshore industry. Increasing the abrasive flow rate beyond the optimum point results in a major reduction in productivity even though the amount of abrasive used is larger. So, this study is intend to find out the optimum abrasive-to-air mixing ratio which can make a significant improvement in blasting efficiency and remarkably reduce the amount of abrasive used. From the test results, it can be identified that as the abrasive feeding rate is increased linearly, blasting efficiency is increased to a maximum point and then gradually decreased in the form of a bell-shaped.

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Vibration Analysis and Diagnosis for Reactor Agitator (Reactor Agitator 의 진동분석 및 진단사례)

  • Yoo, Ju-Hyung;Jung, Goo-Choong;Lee, Sun-Hwi
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2012.04a
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    • pp.107-112
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    • 2012
  • All chemical processes are centered in the chemical reactor. Chemical reactions are often accompanied by mixing. Mixing can influence not just reaction rate but also product distribution if more than one product is possible. So, reactor agitator is more critical in industrial reactions. High vibration was occurred on reactor agitator which is critical equipment in HDPE plant. This paper describes analysis and diagnosis for agitator vibration throughout some tests. High vibration has been occurred by misalignment and resonance. Through the correction it could be stable.

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Mixing Process of Double Diffusive Salt Wedge (이중확산의 영향을 받는 염수침입의 혼합과정 연구)

  • Hwang, Jin-Hwan
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.11 no.2
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    • pp.92-97
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    • 2008
  • Salt wedge into the river from the sea or fresh water flume (fresh wedge) in the ocean from the sea has density current characteristics. However, when temperature and salinity simultaneously determine the density of wedges, one of salinity and temperature can distributed in the reversed profiles against gravity, even though the density profile is stable. In this case, the double diffusive process is critical in determining mixing rate. The present work studies relative contribution of shear driven mechanical mixing component and double diffusive layering process, when warm salty denser water is introduced into the cold fresh lighter water column. Laboratory experiment releases warm salty denser water into cold fresh lighter water controlling discharge amount to achieve the steady state of density current. When longitudinal density rate becomes 15, the released amount ratio of salt and heat changes sharply and in the releasing point, vigorous mixing occurs with increase of discharged amount due to double diffusion. Double diffusion distabilizes gravitational stability and enhances the mixing rate up to $6{\times}10$ times at the lower density ratio comparing to the higher density ratio.

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Case Studies of Penetration Characteristics of DCM Wall Using Spiral Mixing Blades in Soil Layers (특수교반날개를 사용한 DCM 공법의 지반 관입 특성에 대한 사례연구)

  • Jung, Doo-Hoi;Jeong, Gyung-Hwan;Yang, Tae-Seon
    • Journal of the Korean Geotechnical Society
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    • v.23 no.3
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    • pp.133-140
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    • 2007
  • DCM (Deep Cement Mixing Method) has been applied to build structures such as self-supported earth retaining walls. DCM columns should be penetrability into the stiff layer to assure the self-supporting ability. On the penetration increase of blade attached to the DCM mixing tools, a spiral mixing blade has been revised. Penetration characteristics of spiral blades in the stiff soil layer were evaluated through Gimhae and Incheon areas. The spiral mixing blades could penetrate into the stiff soil layers which have the N-value of greater than 30 although the penetration rate is somewhat slow. Penetration characteristics and economical efficiency should be discussed to determine the critical depth of the spiral mixing blade because the penetration efficiency can decrease in the stiff layer in this paper.

Experimental Studies on the Properties of Epoxy Resin Mortars (에폭시 수지 모르터의 특성에 관한 실험적 연구)

  • 연규석;강신업
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.26 no.1
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    • pp.52-72
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    • 1984
  • This study was performed to obtain the basic data which can be applied to the use of epoxy resin mortars. The data was based on the properties of epoxy resin mortars depending upon various mixing ratios to compare those of cement mortar. The resin which was used at this experiment was Epi-Bis type epoxy resin which is extensively being used as concrete structures. In the case of epoxy resin mortar, mixing ratios of resin to fine aggregate were 1: 2, 1: 4, 1: 6, 1: 8, 1:10, 1 :12 and 1:14, but the ratio of cement to fine aggregate in cement mortar was 1 : 2.5. The results obtained are summarized as follows; 1.When the mixing ratio was 1: 6, the highest density was 2.01 g/cm$^3$, being lower than 2.13 g/cm$^3$ of that of cement mortar. 2.According to the water absorption and water permeability test, the watertightness was shown very high at the mixing ratios of 1: 2, 1: 4 and 1: 6. But then the mixing ratio was less than 1 : 6, the watertightness considerably decreased. By this result, it was regarded that optimum mixing ratio of epoxy resin mortar for watertight structures should be richer mixing ratio than 1: 6. 3.The hardening shrinkage was large as the mixing ratio became leaner, but the values were remarkably small as compared with cement mortar. And the influence of dryness and moisture was exerted little at richer mixing ratio than 1: 6, but its effect was obvious at the lean mixing ratio, 1: 8, 1:10,1:12 and 1:14. It was confirmed that the optimum mixing ratio for concrete structures which would be influenced by the repeated dryness and moisture should be rich mixing ratio higher than 1: 6. 4.The compressive, bending and splitting tensile strenghs were observed very high, even the value at the mixing ratio of 1:14 was higher than that of cement mortar. It showed that epoxy resin mortar especially was to have high strength in bending and splitting tensile strength. Also, the initial strength within 24 hours gave rise to high value. Thus it was clear that epoxy resin was rapid hardening material. The multiple regression equations of strength were computed depending on a function of mixing ratios and curing times. 5.The elastic moduli derived from the compressive stress-strain curve were slightly smaller than the value of cement mortar, and the toughness of epoxy resin mortar was larger than that of cement mortar. 6.The impact resistance was strong compared with cement mortar at all mixing ratios. Especially, bending impact strength by the square pillar specimens was higher than the impact resistance of flat specimens or cylinderic specimens. 7.The Brinell hardness was relatively larger than that of cement mortar, but it gradually decreased with the decline of mixing ratio, and Brinell hardness at mixing ratio of 1 :14 was much the same as cement mortar. 8.The abrasion rate of epoxy resin mortar at all mixing ratio, when Losangeles abation testing machine revolved 500 times, was very low. Even mixing ratio of 1 :14 was no more than 31.41%, which was less than critical abrasion rate 40% of coarse aggregate for cement concrete. Consequently, the abrasion rate of epoxy resin mortar was superior to cement mortar, and the relation between abrasion rate and Brinell hardness was highly significant as exponential curve. 9.The highest bond strength of epoxy resin mortar was 12.9 kg/cm$^2$ at the mixing ratio of 1:2. The failure of bonded flat steel specimens occurred on the part of epoxy resin mortar at the mixing ratio of 1: 2 and 1: 4, and that of bonded cement concrete specimens was fond on the part of combained concrete at the mixing ratio of 1 : 2 ,1: 4 and 1: 6. It was confirmed that the optimum mixing ratio for bonding of steel plate, and of cement concrete should be rich mixing ratio above 1 : 4 and 1 : 6 respectively. 10.The variations of color tone by heating began to take place at about 60˚C, and the ultimate change occurred at 120˚C. The compressive, bending and splitting tensile strengths increased with rising temperature up to 80˚ C, but these rapidly decreased when temperature was above 800 C. Accordingly, it was evident that the resistance temperature of epoxy resin mortar was about 80˚C which was generally considered lower than that of the other concrete materials. But it is likely that there is no problem in epoxy resin mortar when used for unnecessary materials of high temperature resistance. The multiple regression equations of strength were computed depending on a function of mixing ratios and heating temperatures. 11.The susceptibility to chemical attack of cement mortar was easily affected by inorganic and organic acid. and that of epoxy resin mortar with mixing ratio of 1: 4 was of great resistance. On the other hand, when mixing ratio was lower than 1 : 8 epoxy resin mortar had very poor resistance, especially being poor resistant to organicacid. Therefore, for the structures requiring chemical resistance optimum mixing of epoxy resin mortar should be rich mixing ratio higher than 1: 4.

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A Case Study on the High-quality DCM applied to the Foundation of Breakwater (방파제 기초에 적용된 고품질 DCM공법의 설계 및 시공 사례)

  • Kang, Yeoun-Ike;Shim, Min-Bo;Shim, Sung-Hyun;Kim, Ha-Young;Shim, Jae-Bum;Chun, Youn-Chul;Yoon, Jung-Ik
    • Proceedings of the Korean Geotechical Society Conference
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    • 2009.09a
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    • pp.815-826
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    • 2009
  • The paper presents a case study addressing the design and construction aspects for DCM(Deep Cement Mixing) method employed as the foundation of a caisson type breakwater with heavy weight(10,700 ton/EA) and a high design wave height($H_{1/3}$=8.7m). The DCM was designed for the project(Ulsan New Port North Breakwater Phase 1) by optimizing the pattern of DCM columns with a combination of short and long columns (i.e., block type(upper 3m)+wall type(lower)) and considering overlapped section between columns as a critical section against shear force where the coefficient of effective width of treated column($\alpha$) was estimated with caution. It was shown that the value can be 0.9 under the condition with the overlapped width of 30cm. In addition to that, a field trial test was performed after improving conventional DCM equipment (e.g., mixing blades, cement paste supplying pipes, multi auger motor, etc.) to establish a standardized DCM construction cycle (withdrawal rate of mixing blades) which can provide the prescribed strength. The result of the field strength test for cored DCM specimens shows that the averaged strength is larger than the target strength and the distribution of the strength(with a defect rate of 7%) also satisfies with the quality control normal distribution curve which allows defect rate of 15.9%.

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Effects of Solids Content and Mixing Speed in Treatment of Petroleum Hydrocarbon Contaminated Soils using a Bioreactor (고형물함량 및 혼합강도가 생물반응기를 이용한 석유계탄화수소 오염토양의 처리에 미치는 영향)

  • 김수철;남궁완;박대원
    • Journal of Korea Soil Environment Society
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    • v.2 no.3
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    • pp.23-30
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    • 1997
  • The purpose of this study was to evaluate effects of solids content and mixing speed in treatment of petroleum hydrocarbon contaminated soils using a slurry-phase bioreactor. Performance results on slurry-phase bioremediation of diesel fuel contaminated soil were generated at the bench-scale level. The fate of TPH(Total Petroleum Hydrocarbon) was evaluated in combination with biological treatment. Abiotic and biotic fate of the TPH were determined using soil not previously exposed to compounds in diesel fuel. The reactor volume for given throughput can be reduced by maximizing the solids content. Applications of 50% and 20% solids content(dry weight basis) were showed a little difference(57.5% : 61.6%) in biological TPH removal rate each other. Mixing and particle suspension are critical to desorption and biological degradation. In this standpoint, this study was performed using two mixing speed. When the reactor was operated at 70rpm, it had a better result in the particle suspension and TPH removal rate than the reactor with mixer rotated at 20rpm. In the reactor applied 20rpm, it was resulted in failure of particle suspension.

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