• Title/Summary/Keyword: manganese zinc ferrite

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Origin of the Initial Permeability of Manganese-Zinc Ferrite Polycrytals (Mn-Zn 페라이트 다결정의 조성에 따른 투자율의 변화 기구)

  • 변순천;제해준;고경현;홍국선
    • Journal of the Korean Ceramic Society
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    • v.34 no.4
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    • pp.351-356
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    • 1997
  • The origin of the variation of initial permeability in manganese-zinc ferrite polycrystals with a content of hematite was investigated. Initial permeability showed maximum with hematite content while there was no significant change in microstructure. Saturation magnetization increased with hematite content. So the variation of initial permeability was not explained on the basis of microstructural change or saturation magnetization. Temperature dependence of initial permeability revealed magnetocrystalline anisotropy was the origin of the variation of initial permeability. The change in magnetocrystalline anisotropy was ascribed to the variation in ferrous ion concentration. Therefore the variation of initial permeability in manganese-zinc ferrite polycrystals with a content of hematite was due to ferrous ion concentration via magnetocrystalline anisotropy.

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Synthesis of Functional Complex Material from Spent Alkaline Manganese Battery (폐(廢)알칼리망간전지(電池)로부터 기능성(機能性) 복합소재(複合素材) 제조(製造))

  • Kim, Tae-Hyun;Lee, Seoung-Won;Sohn, Jeong-Soo;Kang, Jin-Gu;Shin, Shun-Myung
    • Resources Recycling
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    • v.17 no.1
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    • pp.66-72
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    • 2008
  • Fundamental studies for the synthesis of Mn-Zn ferrite powder were investigated using a series of leaching and coprecipitation processes from spent alkaline manganese batteries. Zinc and Manganese dissolution rates obtained at the reaction conditions of 100g/L pulp density, 3.0M $H_2SO_4$, $60^{\circ}C$ and 200 rpm with 30 ml $H_2O_2$ as a reducing agent were more than 97.9% and 93.9% and coprecipitation of Mn-Zn ferrite powder was performed according to various reaction conditions such as temperature, time and amount of $O_2$ gas injection using the leaching solution. As a result of coprecipitation, Mn-Zn ferrite could be synthesized directly at low temperature in the reaction condition pH 12, $80^{\circ}C$, $O_2$ 1.3 L/min. and 400 rpm. The synthesized Mn-Zn ferrite powder was spherical powder of $0.143{\mu}m$ particle size and had a saturation magnetization about 80 emu/g.

Effect of pH on the Preparation of Manganese Zinc Ferrite Powder by Alcoholic Dehydration of Citrate/formate Solution (알콜 탈수법에 의한 Mn-Zn Ferrite 분체 제조시 pH의 영향)

  • 김창범;신효순;이대희;김창현;이병교
    • Journal of the Korean Ceramic Society
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    • v.32 no.10
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    • pp.1123-1130
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    • 1995
  • In the preparation of manganese zinc ferrite powders by alcoholic dehydration of citrate/formate solution. The effect of pH change on precipitation was investigated. The pH range for obtaining stable precipitates was studied. The glassy phase was obtained when the pH value of solution is higher than 5, and the formation mechanism of glassy phase was suggested. Below pH 5, the stable precipitates were formed, and the optimal pH was 2. Formation of glassy phase was accounted for the change of surface charge by pH change. The change of surface charge is caused by the interparticular agglomeration. The precipitate was redissolved into the water on the surface of precipitate itself and through the polymerization, it agglomerated. This mechanism is tought to be similar to that of viscous flow.

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Crystallographic and Magnetic Properties of Co, Zn, Ni-Zn Substituted Nano-size Manganese Ferrites Synthesized by Sol-gel Method

  • Noh, Kwang Mo;Lee, Young Bae;Kwon, Woo Hyun;Kang, Jeoung Yun;Choi, Won-Ok;Chae, Kwang Pyo
    • Journal of Magnetics
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    • v.21 no.3
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    • pp.308-314
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    • 2016
  • Cobalt-, zinc-, and nickel-zinc-substituted nano-size manganese ferrite powders, $MnFe_2O_4$, $Mn_{0.8}Co_{0.2}Fe_2O_4$, $Mn_{0.8}Zn_{0.2}Fe_2O_4$ and $Mn_{0.8}Ni_{0.1}Zn_{0.1}Fe_2O_4$, were fabricated using a sol-gel method, and their crystallographic and magnetic properties were subsequently studied. The $MnFe_2O_4$ ferrite powder annealed at temperatures above 523 K exhibited a spinel structure, and the particle size increased as the annealing temperature increased. All ferrites annealed at 773 K showed a single spinel structure, and the lattice constants and particle size decreased with the substitution of Co, Zn, and Ni-Zn. The $M{\ddot{o}}ssbauer$ spectrum of the $MnFe_2O_4$ ferrite powder annealed at 523 K only showed a doublet due to its superparamagnetic phase, and the $M{\ddot{o}}ssbauer$ spectra of the $MnFe_2O_4$, $Mn_{0.8}Co_{0.2}Fe_2O_4$, and $Mn_{0.8}Zn_{0.2}Fe_2O_4$ ferrite powders annealed at 773 K could be fitted as the superposition of two Zeeman sextets due to the tetrahedral and octahedral sites of the $Fe^{3+}$ ions. However, the $M{\ddot{o}}ssbauer$ spectrum of the $Mn_{0.8}Ni_{0.1}Zn_{0.1}Fe_2O_4$ ferrite powder annealed at 773 K consisted of two Zeeman sextets and one quadrupole doublet due to its ferrimagnetic and paramagnetic behavior. The area ratio of the $M{\ddot{o}}ssbauer$ spectra could be used to determine the cation distribution equation, and we also explained the variation in the $M{\ddot{o}}ssbauer$ parameters by using this cation distribution equation, the superexchange interaction and the particle size. Relative to pure $MnFe_2O_4$, the saturation magnetizations and coercivities were larger in $Mn_{0.8}Co_{0.2}Fe_2O_4$ and smaller in $Mn_{0.8}Zn_{0.2}Fe_2O_4$, and $Mn_{0.8}Ni_{0.1}Zn_{0.1}Fe_2O_4$. These variations could be explained using the site distribution equations, particle sizes and magnetic moments of the substituted ions.

Manganese Zinc Ferrite Singel Crystal Growth by Continuous Crystal Growing Method (연속성장법에 의한 Mn-Zn Ferrite 단결정 성장)

  • 정재우;오근호
    • Journal of the Korean Ceramic Society
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    • v.29 no.7
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    • pp.539-543
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    • 1992
  • The continuous growth method was developed for Mn-Zn Ferrite single crystals. It is a new process that the polycrystalline MnχZn1-χFe2O4 raw materials are supplied continuously from the powder feeding system to the crucible heated by R.F. induction and melted in the crucible, and after the single crystals seed is attached to crucible's hole, the crystals are pulled downward with rotation. Growing the crystals by using the growth method different from the conventional Bridgman or Floating Zone method, we defined the factors having effect on the crystal growing through the pre-experiments. They are temperature distribution in the crucible, melt velocity according to its height, wettability between the crucible's bottom and melt. Therefore, Mn-Zn Ferrite single crystals were to be grown by attaining the appropriate melt height in the crucible, powder feeding rate, temperature gradient between the crucible and interface, crystal growing speed, and this method was confirmed to have possibility for single crystal growing.

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Effect of CaO and $SiO_2$ Addition on the Electromagnetic Properties of Mn-Zn Ferrites ($SiO_2$와 CaO 첨가가 Mn-Zn Ferrites의 전자기적 물성에 미치는 영향)

  • 서정주;신명승;한영호
    • Journal of the Korean Ceramic Society
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    • v.32 no.9
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    • pp.1033-1039
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    • 1995
  • The current experiment has quantitatively investigated the effect of the content of CaO and SiO2 on the microstructure, density, electrical resistivity, power loss and initial permeability of manganese zinc ferrites. The density increased initially with CaO and SiO2 content and the further addition showed an adverse effect. The excess addition of CaO and SiO2 developed a discontinuous grain growth with numerous pores inside grains and lowered the electrical resistivity. The initial permeability decreased with increasing the content of SiO2. The samples with relatively low power loss showed that half of the total loss at 10$0^{\circ}C$, 100 kHz and 2000 Gauss was due to the eddy current loss.

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Effect of Aggregates on the Microstructure in Manganese Zinc Ferrite

  • Shin, Hyo-Soon;Lee, Dae-Hee;Kim, Chang-Bum;Kim, Nam-Kyung;Lee, Suk-Kee;Lee, Byung-Kyo
    • Journal of the Korean Ceramic Society
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    • v.40 no.1
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    • pp.1-4
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    • 2003
  • To study the effect of aggregates on the microstructure of sintered bodies, Mn-Zn ferrite powders were prepared by an alcoholic dehydration method. Aggregate powders and reground powders were used as seeds and matrices, respectively. The mixing ratios for the aggregate and reground powders were varied with the sintering temperatures. Green densities were measured with changes in forming pressure and they were related to the microstructures of the sintered bodies. The aggregates proved to be capable of acting as seeds for abnormal grain growth. When the green density difference between the aggregate and the matrix was large, the aggregate could become the seed of abnormal grain growth. As the forming pressure increased, the more aggregates became seeds of abnormal grain growth.

Origin of Variation of the Initial Permeability of Manganese-Zinc Ferrite Polycrystals with Additives (Mn-Zn 페라이트 다결정의 첨가물에 따른 초투자율의 변화 기구)

  • Byeon, Sun-Cheon;Byeon, Tae-Yeong;Go, Gyeong-Hyeon;Hong, Guk-Seon
    • Korean Journal of Materials Research
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    • v.7 no.9
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    • pp.758-762
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    • 1997
  • 52mol% Fe$_{2}$O$_{3}$, 26mol% MnO의 조성에서 calcium과 vanadium의 동시첨가에 의한 투자율의 변화원인을 살펴보았다. 초투자율은 첨가물의 농도가 커짐에 따라 감사하였으나 소결체의 밀도나 입자크기는 증가하였으므로 초투자율의 변화는 미세구조의 변화로는 설명되지 않았다. 전기비저항은 첨가물의 농도가 증가함에 따라 증가하였으며 이는 입계의 고저항층의 생성과 vanadium ion에 의한 Fe$^{2+}$이온의 산화로 설명되었다. 첨가물의 농도가 증가함에 따라, 초투자율의 제 2차 최대치가 나타나지 않는 것과 초투자율이 감소하는 것으로부터, 결정자기이방성 상수의 값은 음으로 커짐을 알 수 있었다. 투자육의 온도의존성과 비저항의 변화로부터, 첨가물의 농도에 따른 상온 초투자율의 감소는 Fe$^{2+}$ 이온 농도의 감소에 따른 결정자기이방성 상수의 증가에 의한 효과와 입계에 유리질이 생겨 자벽이 쉽게 이동하지 못하는 효과 때문인 것으로 판단되었다.

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