DOI QR코드

DOI QR Code

Flame Retardancy of Zelkova Sarrata Treated with Ammonium Salts

암모늄염으로 처리된 느티나무의 난연성 시험

  • Chung, Yeong-Jin (Dept. of Fire & Disaster Prevention, Kangwon National University,)
  • 정영진 (강원대학교 소방방재공학과)
  • Received : 2010.09.06
  • Accepted : 2010.11.09
  • Published : 2010.12.31

Abstract

This study was performed to test the flame retardancy of zelkova sarrata-based materials by the treatment of ammonium salts. Zelkova sarrata plate was soaked by the treatment with three 20 wt% ammonium salt solutions consisting ammonium chloride (AMSL), monoammonium phosphate (MAPP), and diammonium phosphate (DAPP), respectively, at the room temperature. After the drying specimen treated with chemicals, combustion properties were examined by the cone calorimeter (ISO 5660-1). When the ammonium salts were used as the retardant for zelkova sarrata, the flame retardancy improved due to the treated ammonium salts in the virgin zelkova sarrata. However the specimen shows increasing CO over virgin zelkova sarrata and It is supposed that toxicities depend on extents. Also, the specimen with ammonium salts showed the higher total smoke release (TSR) than that of virgin plate. Of specimens treated with ammonium salts the ammonium chloride handled the test side was considered a improved inhibitory effect of combustion.

Keywords

References

  1. E. Baysal, M. Altinok, M. Colak, S. K. Ozaki, and H. Toker, Fire Resistance of Douglas Fir (Psedotsuga menzieesi) Treated with Borates and Natural Extractives, Bioresour. Technol., 98, 1101 (2007). https://doi.org/10.1016/j.biortech.2006.04.023
  2. S. L. LeVan, "Chemistry of Fire Retardancy", ed. R. Rowell, The Chemistry of Solid Wood, p.531, Americ an Chemical Society, Washington D. C. (1984).
  3. R. Kozlowski and M. Helwig, "Progress in Flame Retardancy and Flammability Testing", 1st Int Conf. Progess in Flame Retardancy and Flammability Testing, Institute of Natural Fibres, Poznan, Poland (1995).
  4. Y. J. Chung, Fire Retardancy of Recycled Polyurethane Foam Containing Phosphorus Compounds, J. of Korean Oil Chemists' Soc., 24(2), 182 (2007).
  5. M. L. Hardy, Regulatory Status and Environmental Properties of Brominated Flame Retardants Undergoing Risk Assessment in the EU: DBDPO, OBDPO, PeBDPO and HBCD, Polym. Degrad. Stab., 64, 545 (1999). https://doi.org/10.1016/S0141-3910(98)00141-4
  6. Y. Tanaka, "Epoxy Resin Chemistry and Technology", Marcel Dekker, Marcel Dekker, New York (1988).
  7. E. Mikkola, "Charring of Wood Based Materials", p.547, Proceedings of the Third International Symposium, Elsevier Applied Science, London (1991).
  8. J. G. Quintiere, "A Semi-quantitative Model for the Burning Rate of Solid Materials", NISTIR 4840, National Institute of Standards and Technology, Gaithersburg, M.D., U.S.A. (1992).
  9. M. J. Spearpoint and G.J. Quintiere, "Predicting the Burning of Wood Using an Integral Model", Combust. Flame, 123, 308 (2000). https://doi.org/10.1016/S0010-2180(00)00162-0
  10. J. J. Brenden, "How nine inorganic salts affected smoke yield from Douglas-fir Plywood", p. 13, U. S. Forest Service, Research Paper FPL-249 (1975).
  11. Y. J. Chung, Flame Retardancy of Veneers Treated by Ammonium Salts, J. Korean Ind. Eng. Chem. 18(3), 251 (2007).
  12. M. M. Hirschler, Fire Hazard and Toxic Potency of the Smoke from Burning Materias, Advances in Combustion Toxicology, 2, 229 (1990).
  13. ISO 5660-1, "Reaction-to-Fire Tests– Heat Release, Smoke Production and Mass Loss Rate – Part 1: Heat Release Rate (Cone Calorimeter Method)" Genever (2002).
  14. M. Hirschler, "Thermal Decomposition and Chemical Composition", p.239, American Chemical Society Symposium Series 797 (2001).
  15. W. T. Simpso, "Wood Handbook-Wood as an Engineering Material", Chap.12, Forest Product Laboratory U.S.D.A., Forest Service Madison, Wisconsine, U.S.A. (1987).
  16. M. Delichatsios, B. Paroz and A. Bhargava, Flammability Properties for Charring Materials, Fire Safety J., 38, 219 (2003). https://doi.org/10.1016/S0379-7112(02)00080-2
  17. V. Babrauskas, "The SFPE Handbook of Fire Protection Engineering", Fourth ed., National Fire Protection Association, Massatusetts, U.S.A. (2008).
  18. J. G. Quintire, "Principles of Fire Behavior", Chap. 5, Cengage Learning, Delmar, U.S.A. (1998).