Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Reusable and Efficient Polystryrene-supported Acidic Ionic Liquid Catalyst for Mononitration of Aromatic Compounds

  • Li, Li Xia (School of Environment, Jiangsu University) ;
  • Ling, Qi Long (School of Chemical Engineering, Nanjing University of Science and Technology) ;
  • Liu, Zu Liang (School of Chemical Engineering, Nanjing University of Science and Technology) ;
  • Xing, Xiao Dong (School of Chemical Engineering, Nanjing University of Science and Technology) ;
  • Zhu, Xiao Qin (School of Chemical Engineering, Nanjing University of Science and Technology) ;
  • Meng, Xiao (School of Chemical Engineering, Nanjing University of Science and Technology)
  • Received : 2012.05.19
  • Accepted : 2012.07.22
  • Published : 2012.10.20
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Abstract

A series of polystyrene-supported 1-(propyl-3-sulfonate)-3-methyl-imidazolium hydrosulfate acidic ionic liquid (PS-$[SO_3H-PMIM][HSO_4]$) catalysts were prepared and tested for mononitration of simple aromatics compounds with nitric acid. It was found that the reactivity of the catalysts increased with increasing $[SO_3H-PMIM][HSO_4]$ content. The para-selectivity was not only related to the $[SO_3H-PMIM][HSO_4]$ content but also the substituent groups in aromatics. A reaction mechanism of nitration over this new catalyst was proposed. The catalytic activity of this catalyst decreased slightly after fifth runs in the synthesis of nitrotoluene.

Keywords

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