Journal of the Korean Recycled Construction Resources Institute (한국건설순환자원학회논문집)

Korean Recycled Construction Resources Institute (한국건설순환자원학회)
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Effect of Types and Replacement Ratio of Alkali Activator on Compressive Strength of Ground Granulated Blast Furnace Slag Mortar

알칼리 자극제의 종류 및 치환율이 고로슬래그 미분말 모르타르의 압축강도에 미치는 영향

  • Kim, Rae-Hwan (Department of Architectural Engineering, Chungnam National University) ;
  • Kim, Gyu-Yong (Department of Architectural Engineering, Chungnam National University) ;
  • Kim, Jong-Hee (Kyeryong Construction Industrial) ;
  • Lee, Bo-Kyeong (Department of Architectural Engineering, Chungnam National University) ;
  • Cho, Bong-Suk (Resources Recycling Research Dept. Environment&Energy Research Center, RIST)
  • Received : 2014.12.20
  • Accepted : 2014.12.26
  • Published : 2014.12.30
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Abstract

In this study, effect of types and replacement ratio of alkali activator on compressive strength of ground granulated blast furnace slag mortar has been reviewed. Types of alkali activator are NaOH, $Ca(OH)_2$, $Na_2SO_4$, and KOH. Replacement ratio of alkali activator is 7.5, 10, 12.5, and 15%, respectively. As results, under high temperature curing condition, 1 day compressive strength development with NaOH and KOH was higher than that of $Ca(OH)_2$ and $Na_2SO_4$. Regardless of types of alkali activator, compressive strength increased with increasing pH. This can be explained by the fact that impermeable film on the surface of slag which is generated when slag contacts water has been destroyed by alkali activator, and this promotes hydration reaction. Also, 1 day age compressive strength of specimen with high temperature curing was higher than that of specimen with standard curing. 28 days age compressive strength of specimen with high temperature curing was less than or equal to that of specimen with standard curing.

본 연구에서는 알칼리 자극제의 종류 및 치환율이 고로슬래그 미분말 모르타르의 압축강도에 미치는 영향에 대해 검토하였다. 알칼리 자극제의 종류는 NaOH, $Ca(OH)_2$, $Na_2SO_4$, KOH의 4수준이며, 치환율은 각각 7.5, 10, 12.5, 15%의 4수준으로 설정하였다. 실험결과, 재령 1일의 표준, 고온양생조건에서 NaOH, KOH가 $Ca(OH)_2$, $Na_2SO_4$에 비해 압축강도의 발현이 크게 나타났다. 알칼리 자극제의 종류에 관계없이 pH가 높을수록 압축강도도 높게 나타나는 경향을 나타냈으며 이는 슬래그가 물과 접하면 슬래그 입자표면에 불투수성 피막이 형성되는데 이러한 불투수성 피막을 알칼리 자극제가 파괴시켜 수화반응을 촉진시킨 것으로 판단된다. 또한 1일 재령의 경우에는 고온양생의 압축강도가 표준양생의 압축강도에 비해 다소 높게 나타났으며 재령 28일의 경우에는 고온양생의 압축강도가 표준양생의 압축강도와 비슷하거나 다소 낮은 결과를 보였다.

Keywords

References

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