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Study on the Removal of Fluorescent Whitening Agent by Pretreatment Ozone Oxidation for MBR Process Application

MBR 공정 적용을 위한 전처리 오존산화에 의한 형광증백제 제거 연구

  • Received : 2017.02.16
  • Accepted : 2017.03.20
  • Published : 2017.03.27

Abstract

In this study, ozone oxidation experiment was carried out for the removal of fluorescent whitening agent which is widely used in textile dyeing and paper industry. The stilbene fluorescent whitening agent has been industrialized since the earliest, and the amount of current production is the highest. Due to the characteristics of the fluorescent whitening agent that can not be removed by conventional wastewater treatment methods, the fluorescent whitening agent in wastewater treatment has difficulty in using as recycled water in the process. Pre-treatment ozone oxidation experiment was conducted prior to the introduction of Membrane Bio Reactor(MBR) treatment process by converting biodegradable materials into biodegradable materials. The removal efficiencies of fluorescent whitening agents, a diaminostilbenedisulfonic acid derivative by ozone oxidation were evaluated by $UV_{254}$ Scan, $COD_{Mn}$, T-N and color using a synthetic wastewater sample ($COD_{Mn}=433.0mg/{\ell}$) and paper and paper mill wastewater ($COD_{Mn}=157.2mg/{\ell}$).

Keywords

References

  1. NIER, "Occurrence and Treatment of Factory Wastewater", Ministry of Environment, Sejong, pp.10-12, 2013.
  2. G. B. Lim, J. Y. Lee, C. H. Kim, S.Y. Kim, and J. H. Park, Study on the Factors Influencing the Fluorescence Index of Internal Fluorescent Whitening Agent, J. of Korea TAPPI, 46(1), 11(2014).
  3. C. H. Kim, J. Y. Lee, B. H. Kim, J. S. Choi, G. B. Lim, and D. M. Kim, Study on the Thermal Fastness of Fluorescent Whitening Agents, J. of Korea TAPPI, 44(1), 10(2012).
  4. H. Zhang, Z. He, Y. Ni, H. Hu, andY. Zhou, "Using Optical Brightening Agents(OBA) for Improving the Optical Properties of HYP-Containing Paper Sheets", Pulp and Paper, Canada, p.20, 2009.
  5. NIER, "Survey on Exposure of Fluorescent Brightener Agents by Products", Korea Environment Corporation, Incheon, p.4, 2007.
  6. I. Karat, "Advanced Oxidation Processes for Removal of COD from Pulp and Paper Mill Effluents", Master of Science Thesis, Stockholm, p.24, 2013.
  7. H. S. Shin and J. L. Lim, Improving Biodegradability of Naphthalene Refinery Process Wastewater by Ozonation, J. of KSEE, 15(2), 478(1993). Textile Coloration and Finishing, Vol. 29, No. 1
  8. I. J. Chin and C. S. Jang, Characterization of Epoxy Cure by Chromophore Labeling Technique, Polymer(Korea), 14(3), 285(1990).
  9. B. U. Cho and J. M. Won, Effect of PVAm Application for Fine Paper on Effectiveness of Optical Brightening Agent, J. of Korea TAPPI, 48(3), 24(2016).
  10. S. S. Kim, M. W. Huh, M. H. Han, J. H. Yun, H. Cho, and D. K. Kim, A Study On the Decomposition Properties of Disperse Dye Ozone Oxidation Treatment and the Optimum Treatment Condition(I), Textile Coloration and Finishing, 8(1), 43(1996).
  11. W. Peng, Y. Chen, S. Fan, F. Zhang, G. Zhang, and X. Fan, Use of 4,4′-Dinitrostilbene-2,2′-Disulfonic Acid Wastewater as a Raw Material for Paramycin Production, Environ. Sci. Technol, 44, 9159(2010).