Journal of Sensor Science and Technology (센서학회지)

The Korean Sensors Society (한국센서학회)
권호 표지
DOI QR코드

DOI QR Code

Optical and Electrochemical Properties of LiNiPO4 Thin Film for Transparent Thin Film Lithium Secondary Battery

투명 박막 리튬이차전지를 위한 LiNiPO4 박막의 광학 및 전기화학적 특성

  • Lee, HyunSeok (Center for Electronic Materials, Korea Institute of Science and Technology) ;
  • Parmar, Narendra S. (Center for Electronic Materials, Korea Institute of Science and Technology) ;
  • Kim, Kwang-Bum (Department of Material science and Engineering, Yonsei University) ;
  • Choi, Ji-Won (Center for Electronic Materials, Korea Institute of Science and Technology)
  • 이현석 (한국과학기술연구원 전자재료연구단) ;
  • ;
  • 김광범 (연세대학교 신소재공학과) ;
  • 최지원 (한국과학기술연구원 전자재료연구단)
  • Received : 2017.12.15
  • Accepted : 2018.01.27
  • Published : 2018.01.31
Download PDF
⟨ Previous Next ⟩

Abstract

Transparent olivine $LiNiPO_4$ thin films on sapphire substrates were fabricated by radio frequency (RF) magnetron sputtering. The X-ray diffraction patterns show these thin films have the phase of $LiNiPO_4$ with an ordered olivine structure indexed to the orthorhombic Pmna space group. $LiNiPO_4$ thin films deposited on sapphire substrates exhibit transmittance of about 83 %. It was confirmed that the $LiNiPO_4$ thin film exhibits a high potential of 5 V-class.

Keywords

References

  1. P. Gorrn, M. Sander, J. Meyer, M. Kroger, E. Becker, H.H. Johannes, W. Kowalsky, and T. Riedl, "Towards seethrough displays: Fully transparent thin-film transistors driving transparent organic light-emitting diodes", Adv. Mater., Vol. 18(6), pp. 738-741, 2006. https://doi.org/10.1002/adma.200501957
  2. S.H. Ju, J. Li, J. Liu, P.C. Chen, Y.G. Ha, F. Ishikawa, H. Chang, C.W. Zhou, A. Facchetti, D. B. Janes, and T. J. Marks, "Transparent active matrix organic light-emitting diode displays driven by nanowire transistor circuitry", Nano Lett., Vol. 8(4), pp. 997-1004, 2008. https://doi.org/10.1021/nl072538+
  3. S.H. Ko Park, C.S. Hwang, J.I. Lee, S.M. Chung, Y.S. Yang, L.M. Do, and H.Y. Chu, "Transparent ZnO thin film transistor array for the application of transparent AMOLED display", SID Symp. Dig. Tech. Pap., Vol. 37, pp. 25- 28, 2012.
  4. Y. Yang, S. Jeong, L. Hu, H. Wu, S. W. Lee, and Y. Cui, "Transparent lithium-ion batteries", PNAS, Vol. 108(32), pp. 13013-13018, 2011. https://doi.org/10.1073/pnas.1102873108
  5. Y. Xu, W.Y. Ching, and Y. Chiang, "Comparative studies of the electronic structure of $LiFePO_4$, $FePO_4$, $Li_3PO_4$, LiMn- PO4, $LiCoPO_4$, and $LiNiPO_4$", J. Appl. Phys., Vol. 95(11), pp. 6583-6585, 2004. https://doi.org/10.1063/1.1667422
  6. A.K. Padhi, K.S. Nanjundaswamy, J.B. Goodenough, "Phospho-olivines as positive-electrode materials for rechargeable lithium batteries", J. Electrochem. Soc., Vol. 144(4), pp. 1188-1194, 1997. https://doi.org/10.1149/1.1837571
  7. B. Zhang, X. Wang, H. Li, X. Huang, "Electrochemical performances of $LiFe_{1−x}Mn_xPO_4$ with high Mn content", J. Power Sources, Vol. 196(16), pp. 6992-6996, 2011. https://doi.org/10.1016/j.jpowsour.2010.10.051
  8. M.R. Roberts, G. Vitins, G. Denuault, and J.R. Owena, "High throughput electrochemical observation of structural phase changes in $LiFe_{1−x}Mn_xPO_4$ during charge and discharge", J. Electrochem. Soc., Vol. 154(4), pp. A381-A386, 2010. https://doi.org/10.1149/1.2454366
  9. G. Kobayashi, A. Yamada, S. Nishimura, R. Kanno, Y. Kobayashi, S. Seki, Y. Ohno, and H. Miyashiro, "Shift of redox potential and kinetics in $Li_x(MnyFe_{1−y})PO_4$", Power Sources, Vol. 189(1), pp. 397-401, 2009. https://doi.org/10.1016/j.jpowsour.2008.07.085
  10. J. Wolfenstine, and J. Allen, "$Ni^{3+}/Ni^2$+ redox potential in $LiNiPO_4$", J. power sources, Vol. 142(1), pp. 389-390, 2005. https://doi.org/10.1016/j.jpowsour.2004.11.024
  11. M. Piana, M. Arrabito, S. Bodoardo, A. D'Epifanio, D. Satolli, F. Croce and B. Scrosati, "Characterization of Phospho- olivines as Materials for Li-ion Cell Cathodes", Ionics, Vol. 8(1), pp. 17-26, 2002 https://doi.org/10.1007/BF02377749
  12. M. Minakshia, P. Singh, D. Appadoo, D. E. Martin, "Synthesis and characterization of olivine LiNiPO4 for aqueous rechargeable battery", Electrochim. Acta, Vol. 56(11), pp. 4356-4360, 2011 https://doi.org/10.1016/j.electacta.2011.01.017
  13. S.P. Ong, V.L. Chevrier, and G. Ceder, "Comparison of small polaron migration and phase separation in olivine $LiMnPO_4$ and $LiFePO_4$ using hybrid density functional theory", Phys. Rev. B, Vol. 83(7), pp. 7-15, 2011.
  14. L. Wang, Y. Huang, R. Jiang, D. Jia, "Preparation and characterization of nano-sized $LiFePO_4$ by low heating solidstate coordination method and microwave heating", Electrochim. Acta, Vol. 52(24), pp. 6778-6783, 2007. https://doi.org/10.1016/j.electacta.2007.04.104
  15. Y. Ge, X. Yan, J. Liu, X. Zhang, J. Wang, X. He, R. Wang, H. Xie, "An optimized Ni doped $LiFePO_4$/C nanocomposite with excellent rate performance", Electrochim. Acta, Vol. 55(20), pp. 5886-5890, 2010. https://doi.org/10.1016/j.electacta.2010.05.040
  16. J. Yang, and J.J. Xu, "Synthesis and characterization of carbon- coated lithium transition metal phosphates $LiMPO_4$ (M = Fe, Mn, Co, Ni) prepared via a nonaqueous sol-gel route", J. Electrochem. Soc., Vol. 153(4), pp. A716-A723, 2006. https://doi.org/10.1149/1.2168410
  17. X. Rui, X. Zhao, Z. Lu, H. Tan, D. Sim, H.H. Hng, R. Yazami, T.M. Lim, and Q. Yan, "Olivine-type nanosheets for lithium ion battery cathodes", ACS Nano, Vol. 7(6), pp. 5637-5646, 2013. https://doi.org/10.1021/nn4022263