Membrane Journal (멤브레인)

The Membrane Society of Korea (한국막학회)
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Recent Advances in Metal Organic Framework based Thin Film Nanocomposite Membrane for Nanofiltration

나노여과를 위한 금속유기구조체 기반 박막 나노복합막의 최근 발전

  • Kim, Esther (Energy and Environmental Science and Engineering (EESE), Integrated Science and Engineering Division (ISED), Underwood International College, Yonsei University) ;
  • Patel, Rajkumar (Energy and Environmental Science and Engineering (EESE), Integrated Science and Engineering Division (ISED), Underwood International College, Yonsei University)
  • 김에스더 (연세대학교 언더우드국제대학 융합과학공학부 에너지환경과학공학) ;
  • 라즈쿠마 파텔 (연세대학교 언더우드국제대학 융합과학공학부 에너지환경과학공학)
  • Received : 2021.02.04
  • Accepted : 2021.02.22
  • Published : 2021.02.28
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Abstract

Advancements in thin-film nanocomposite (TFN) membrane technology for nanofiltration is crucial for removing pollutants from natural resources. In recent years, various metal-organic framework (MOF) modifications have been tested to overcome the drawbacks that are inevitable with conventional thin-film composite (TFC) and TFN membranes. In general, MIL-101(Cr), UiO-66, ZIF-8, and HKUST-1 [Cu3(BCT2)] are MOFs that were proven to exhibit excellent membrane performance in terms of solvent permeability and solute rejection; their respective studies are reviewed in this article. Other novelties, such as the simultaneous use of different MOFs and unique MOF layering techniques (e.g., dip-coating, spray pre-disposition, Langmuir-Schaefer film, etc.) are also discussed as they present alternate solutions for membrane enhancement and/or preparation convenience. Not only are these MOF-modified TFN membranes frequently shown to improve separation performance from their respective TFC and TFN membranes, but many reports also explain their potential for a cost-effective and environmentally friendly process. In this review the thin film nanocomposite nanofiltration membrane is discussed.

나노여과를위한 박막 나노복합체(TFN) 멤브레인 기술의 발전은 천연 자원에서 오염 물질을 제거하는 데 중요하다. 최근에는 기존의 박막 복합체(TFC) 및 나노복합체 멤브레인에서 불가피한 단점을 극복하기 위해 다양한 금속유기구조체(MOF) 수정이 테스트되었다. 일반적으로 MIL-101(Cr), UiO-66, ZIF-8 및 HKUST-1 [Cu3(BCT2)]은 용매 투과성 및 용질 제거 측면에서 막 성능을 현저하게 향상시키는 것으로 입증되었다. 이 리뷰에서는 이러한 MOF가 나노 여과에 미치는 영향에 대한 최근 연구가 논의될 것이다. 서로 다른 금속유기구조체의 동시 사용 및 고유한 금속유기구조체 레이어링 기술(예: 딥 코팅, 스프레이 사전 배치, Langmuir-Schaefer 필름 등)과 같은 다른 새로운 기능도 멤브레인 성능을 향상시켰다. 이러한 MOF 변형 TFN 멤브레인은 각각의 TFC 및 TFN 멤브레인에서 분리 성능을 향상시키는 것으로 자주 나타났을 뿐만 아니라 많은 보고서에서 비용 효율적이고 환경 친화적인 공정에 대한 잠재력을 설명한다.

Keywords

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