한국연소학회 2004년도 제28회 KOSCO SYMPOSIUM 논문집
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The lift-off characteristics of the triple flame have been studied experimentally with various mean velocities and concentration gradients using a multi-slot burner, which can control the concentration gradient and the mean velocity independently, Lift-off height, axial maximum velocity, flame temperature, and some other characteristics were examined for methane and propane flame, It was found that minimum values of the lift-off heights exist at a certain concentration gradient for constant mean velocity, and this result implies that the propagation velocity has a maximum value at this condition, OH radical distribution was measured with LIF method and velocity variation along streamline was measured with PlV system. In addition maximum temperature along streamline was measured with CARS system. The intensity of the diffusion flame affects on the propagation velocity of triple flame in the region of very weak concentration gradient.
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Characteristics of turbulent lifted flames in coflow jet have been investigated by varying initial temperature through the heating of coflow air. In the turbulent regime, liftoff height increases linearly with fuel jet velocity and decreases nonlinearly as the coflow temperature increases. This can be attributed to the increase of turbulent propagation speed, which is strongly related to laminar burning velocity. Dimensionless liftoff heights are correlated well with dimensionless jet velocity, which are scaled with parameters determining local flow velocity and turbulent propagation speed. This implies that the turbulent lifted flames are stabilized by balance mechanism between local turbulent burning velocity and flow velocity. Blowout velocity can be obtained from the ratio of mixing time to chemical time. Comparing to previous researches, thermal diffusivity should be evaluated from the initial temperature instead of adiabatic flame temperature.
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Characteristics of laminar lifted names in coflow jet with various coflow velocities have been studied experimently. USlI1g the fuel nozzle with d=0.254 for the pure propane, liftoff heights are fitted by using power equation with jet velocity. As coflow velocity increases up to 60 cm/s powers of fitting equation steeply decrease. From the result of numerical analysis using the FLUENT, the stoichiometry contour and the axial velocity nondimensionalized by initial jet velocity along the stoichiometry contour are changed with variations of coflow velocities, The change of axial velocity along stoichiometric contour is more sensitive than that of stoichiometric contour, For this reason, powers of fitting equation for liftoff height with jet velocity decreases with the increase of coflow velocity. Using the fuel nozzle with d=4,35 mm for the highly diluted propane by nitrogen, the liftoff height increases with the increase of coflow velocity when coflow velocity is less than the maximum value of initial jet velocity. But when coflow velocity is faster than that, the liftoff height decreases with the increase of coflow velocity.
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The Noise generation mechanisms of propane laminar premixed flames on a slot burner have been studied experimentally. The sound levels and frequencies were measured for various mixture flow rates (velocities) and equivalence ratios. The primary frequency of self-induced noise increases with the mean velocity of mixture as
$f{\;}{\propto}{\;}U_f^{1.144}$ and the measured noise level increases with the mixture flow rate and equivalence ratio as$p{\;}{\propto}{\;}U_f^{1.7}$ $F^{8.2}$ . The nature of flame oscillation and the noise generation mechanisms are also investigated using a high speed CCD camera and a DSRL camera. The repetition of sudden extinction at the tip of flame is evident and the repetition rates are identical to the primary frequencies obtained from the FFT analysis of sound pressure signals. CH chemiluminescence intensities of the oscillating flames were also measured by PMT with a 431 nm(10 FWHM) band pass filter and compared to the pressure signals. -
Quenching phenomena is one of major concern in development of millimeter or sub-millimeter scale micro combustor for the size of the combustor is near extinction condition. In this work we focused on the effect of combustor wall condition that was parameterized by Perovskite LSC(
$La_{0.8}$ $Sr_{0.2}$ $CoO_3$ ) redox catalyst. The experiment was done by variable gap-width 2D wall equipment. The flame was produced by premixed methane-air jet issuing from millimeter-scale slot burner and it propagated through the narrow gap of the walls. By comparison of flame behaviour near catalyst-coated wall and simple glass wall, we investigated the effect of possible surface reaction on quenching phenomena. The flame between two plates was observed where the gap of the plates was reduced stepwise from 20mm to a distance of quenching occurrence. The two flames with and without surface modification were almost same by observation. But the gap for the occurrence of quenching was increased between catalyst-coated wall. So we concluded that surface reaction close to combustor wall has a negative effect on micro combustion. -
Lean laminar premixed propane and methane flames which were anchored by a hydrogen-pilot flame in a tube were investigated experimentally. The flame shapes were observed by varying mean velocity from 10cm/s to 140cm/s and equivalence ratio from 0.45 to 0.8. In this study, behaviors of flames are divided into five regions such as tail-out, flash-back, flickering, stable and vibrating flames with respect to the mean velocity and the equivalence ratio. Although the flames are unstable in both the flickering and the vibrating region, they have different characteristics such as the frequency, sound generation and creation process of flame curvature. The flickering region exists near the flammability limit and the flame flickers in a frequency of about 10Hz. When flame front is bended, the propane flame front is straightened and the methane flame front is bended more by thermo-diffusive instability. In the vibrating region, the flame vibrates emitting audible sound in a frequency of about 100Hz. In the boundary of vibrating region, the vibration of flame changes between two modes such as single frequency vibration and dual frequency vibration. Increase and decrease of vibration in each mode are determined by thermo-acoustic instability.
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A two-dimensional twin-jet counterflow system has been designed, in which two streams from two double-slit nozzles form a counterflow. This flow system enables one to systematically investigate various effects on non-premixed flames, including the non-premixed flame interaction, the edge flame behavior and the effect of curvature. Non-premixed flame interaction in the twin-jet counterflow system has been investigated numerically for methane fuel diluted with nitrogen. Three types of non-premixed flame(conventional counterflow flame, crossed twin-jet flame and petal shaped flame) were simulated depending on the combination of fuel/oxidizer supply to each nozzle. The extinction characteristics of non premixed methane flame in the twin-jet counterflow have been investigated numerically. The boundary of the existence of petal-shaped flames was identified for the twin-jet counterflow flames. Due to the existence of the unique petal-shaped flames, the extinction boundary for the twin-jet counterflow can be extended significantly compared to that for the conventional counterflow non-premixed flames, through the interaction of two flames. Through the comparison of the crossed twin-jet flame and the conventional counterflow flame, structure of the crossed twin-jet counterflow flame is analysed. Through the comparison of the petal shaped flame and the conventional counterflow flame, the extension of the extinction boundary for the twin-jet counterflow is investigated.
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A two-dimensional direct numerical simulation was performed to investigate the flame behaviors of
$CH_4/N_2$ -Air counterflow nonpremixed flame interacting with a single vortex. The detailed transport properties and a modified 16-step augmented reduced mechanism based on Miller and Bowman's detailed reaction mechanism are adopted in this calculation. The results showed that an initially flat stagnation plane, on which an axial velocity was zero, was deformed into a complex-shaped plane, and an initial stagnation point was moved far away from a vortex head when the counterflow field was perturbed by the vortex. It was noted that the movement of stagnation point could alter the species transport mechanism to the flame surface. It was also identified that the altered species transport mechanism affected the distributions of the mixture fraction and the scalar dissipation rate. -
Numerical analysis code has been developed for investigating the combustion characteristics in a slab heater of a steel mill company. Unsteady full 3-Dimensional behaviour can be predicted with the code. Premixed flame model is adopted for combustion phenomena. And eddy dissipation model is used for turbulent flow and non gray FVM method for radiation. Slab movement can be fully traced from entrance into heater until it's exit and computation is performed during that period. Code was validated by comparing the calculation results with experimental ones for the bench scale heater.
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The conditional moment closure(CMC) model has been implemented in context with the unstructured-grid finite-volume method which efficiently handle the physically and geometrically complex turbulent reacting flows. The validation cases include a turbulent nonpremixed
$CO/H_2/N_2$ Jet flame and a turbulent nonpremixed$H_2/CO$ flame stabilized on an axisymmetric bluff-body burner. In terms of mean flame field, minor species and NO formation, numerical results has the overall agreement with expermental data. The detailed discussion has been made for the turbulence-chemistry interaction and NOx formation characteristics as well as the comparative performance for CMC and flamelet model. -
High voltage AC electric field has been applied to turbulent propane jets to investigate the effect of electric field on liftoff characteristics. Liftoff velocity and liftoff height have been measured by varying the applied voltage and frequency. Liftoff velocities were delayed and liftoff heights were reduced by applying AC, not by DC. The electric effect became disappeared with further increasing jet velocities, which shows that the effect can be explained by the balance between inertia force and electric force. The flame stabilization effect was intensified as either applied voltage or frequency increased. Plasma streamers were generated between the flame and the jet under high voltage conditions. Liftoff velocity in the absence of plasma can be well correlated by the function of voltage and frequency.
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This work describes a model development and numerical simulation of detailed combustion mechanisms of RDX/GAP/BTIN propellants. The analysis is based on the conservation equations of mass, energy, and species concentrations for both the condensed and gas phases, and takes into account finite-rate chemical kinetics and variable thermophysical properties. The model has been applied to study the combustion wave structures and burning characteristics of RDX/GAP/BTIN propellants over a broad range of pressures. Reasonably good agreement is achieved between the calculated and measured burning rate at atmospheric pressure. But the model calculation does not result in dark zone experimentally observed.
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Dynamic behavior of diffusive-thermal instability in diluted
$CH_4/O_2$ diffusion flames is numerically investigated by adopting detailed chemistry and transport. Counterflow diffusion flame is adopted as a model flamelet. Particular attention is focused on the pulsating-instability regime, which arises for Lewis numbers greater than unity, and the instability occurs at high strain rate near extinction condition in this flame configuration. Once a steady flame structure is obtained for a prescribed value of initial strain rate. transient solution of the flame is calculated after a finite amount of strain-rate perturbation is imposed Oil the steady flame. Transient evolution of the flame depends on the initial strain rate and the amount of perturbed strain rate. Basically, the dynamic behaviors can be classified into two types, namely non-oscillatory decaying solution and diverging solution leading to extinction. The peculiar oscillatory solution. which has been found in the previous study adopting one-step chemistry and constant Lewis numbers, is not observed in this study, which is attributed to both convective flow and preferential diffusion effects. -
Partial quenching structure of turbulent diffusion flames in a turbulent mixing layer is investigated by the method of flame hole dynamics to develope a prediction model for the turbulent lift off. The present study is specifically aimed to remedy the problem of the stiff transition of the conditioned partial burning probability across the crossover condition by adopting level-set method which describes propagating or retreating flame front with specified propagation speed. In light of the level-set simulations with two model problems for the propagation speed, the stabilizing conditions for a turbulent lifted flame are suggested. The flame hole dynamics combined with level-set method yields a temporally evolving turbulent extinction process and its partial quenching characteristics is compared with the results of the previous model employing the flame-hole random walk mapping. The probability to encounter reacting' state, conditioned with scalar dissipation rate, demonstrated that the conditional probability has a rather gradual transition across the crossover scalar dissipation rate in contrast to the stiff transition of resulted from the flame-hole random walk mapping and could be attributed to the finite response of the flame edge propagation.
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The effects of laser heating on soot formation and oxidation of propylene diffusion flames have been studied experimentally under nearly sooting conditions. The non-sooting flame can be converted to a sooting flame when the laser light heats up a flame at 7 mm height, while a sooting flame can be changed to a non-sooting flame when a flame is heated with laser light at flame height of 13 mm. The selective heating at the soot formation and/or oxidation region determines the sooting behavior of a diffusion flame. The increased soot/flame temperatures are most likely to be responsible for both the decreased and increased soot formation/oxidation.
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The combustion characteristics of 0.03MW turbulent methane/oxygen diffusion flames have been investigated to give basic informations for designing industrial oxyfuel combustors. NOx reduction has become one of the most determining factors in the combustor design since 3-5% nitrogen is intrinsically included from the current oxygen producing processes. Flame lengths and NOx concentrations were measured by varying flow velocities with and without installing quarls. Flame stabilities are significantly enhanced by oxyfuel combustion in contrast to air-fuel combustion. Flame length decreases with increasing fuel or oxygen velocity because of the enhancement of turbulent mixing. NOx concentration was reduced with increasing flo velocities. This can be attributed to the entrainment of inert product gases into flame decreasing flame temperature. The installation of quarl on the burners rather increased NOx concentration since the quarl blocked the entrainment above the nozzles.
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Activation energy asymptotics (AEA) for Linan's diffusion-flame regime is revisited in this paper. The main purpose of the paper is to carefully re-examine each AEA analysis step in order to clarify the some concepts that are often misunderstood among the ordinary practitioners of the AEA. Particular attention is focused on the different AEA regimes arising from the double limit of large Zel'dovich and Damkohler numbers. In addition. the expansion procedures are shown in detail and the method that the turning point condition, commonly known as the Linan's extinction condition, is found is explained.
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The present study is focused on the small scale turbulent mixing processes in the scalar field. In order to deal with molecular mixing in turbulent flow, the linear eddy model is addressed. In each realization, the molecular mixing term is implemented deterministically, and turbulent stirring is represented by a sequence of instantaneous, statistically independent rearrangement event called by triplet map. The LEM approach is applied with relatively simple conditions. The characteristics of scalar mixing and PDF profiles are addressed in detail.
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Coal combustion in an iron ore sintering bed is a key parameter that determines quality of the sintered ores and productivity of the process. In this study, effects of the different types of coal coke and anthracite - on the combustion in the iron ore sintering bed are investigated by modeling and experiment. Fuel characteristics of coke and anthracite are observed through a few basic analysis and thermo-gravimetric analysis. It was found that coke has a higher reactivity than anthracite due to the difference of surface area and density. Those characteristics are reflected to the 1-D unsteady simulation of the iron ore sintering bed. Calculation results show that different reactivity of the fuel can affect the bed combustion, which implies the further investigation should be performed for obtaining optimal combustion conditions in the sintering bed.
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In the present paper we studied experimentally fundamental optimization of oxygen enriched pyrolysis melting incinerator, Characteristics of this system was confirmed dealing with the gas flow and combustion properties for the inside secondary air injection. The experiment setup has a disposal rate of 30kg/hr which was measured by the inside temperature and gas. Along with above experiments, the three-dimensional computation was employed to analyse the combustion fluid dynamics and gas residence time. Equations for turbulence and heat - transmission as well as chemical reactions were solved by using common codes. The experimental combustion chamber was composed of staged combustion types structure for reducing NOx. Finally, it was verified that the control of the secondary air and air ratio of thermo stack were important. In the computational analysis, it showed reasonable agreement with the experimental results regarding the temperature and discharged gas concentration.
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In the present work, the numerical model was refined to predict the thermal analysis of energy storage in a fixed beds during charging mode. The governing energy equations of both fluid and the solid particles along with their initial and boundary conditions are derived using a two-phase, one dimensional model. The refined model is carried out by taking into account change of (air density , air specific heat) with air temperature and also by taking into considerations heat losses from bed to surrounding. Finite difference method was used to obtain solution of two governing energy equations of both fluid and solid particles through a computer program especially constructed for this purpose. The temperature field for the air and the solid are obtained, also energy stored inside the bed is computed. A comparison between refined model and non refined model is done. Finally using refined model the effect of bed material (Glass, Fine clay ,and aluminum ), and air flow rate per unit area Ga (0.3, 0.4, and 0.5 kg/
$m^2$ -s) on energy storage characteristics was studied. -
Co-incineration of coal and wastewater sludge was r;erfonn:rl in a O.lMWth bench scale circulating fluidized bed combustor(CFBC) Sludge was received from a wastewater treatment plant in a dye industrial complex in Busan. Metropolis. Moisture content of received sludge was 80%. Coal and sludge mixture was prepared with weight ratio of 90/10, 85/15 and 80/20. Co-combustion characteristics of the coal and sludge mixture demonstrated stable combustion conditions. Component analysis, incineration characteristics, boiler performance was measured before and after the test and application for commercial 59MWth CFBC boiler. The release of hazardous components such as
$SO_2$ and Cl was suppressed by the presence of inherent minerals of Ca, Na, K in coal and sludge mixture. Pre-drying was not essential but it was recommended for the benefits of manageability of sludge. -
Combustion of refuse derived fuel(RDF) and refuse plastic fuel (RPF) was carried out in a lab-scale circulating fluidized bed. Experiment was investigated cold flow visualization. RDF was made by C & tech and RPF was made by KRS. The results include distribution of temperature in the combustion chamber, and concentrations of flue gas such as
$O_2$ ,$CO_2$ , CO,$NO_x$ and HCs Micro G.C(gas chromatograph) was employed to find out concentration of He Temperature distribution was different when RDF and RPF were burnt respectably. As air ratio became increased,$CO_2$ , CO, and total of HCs emissions were decreased. According to the number of carbon atom of HCs, HC were classified as five kinds of HC. -
The burning characteristics of interacting droplets with internal circulation in a convective flow are numerically investigated at various Reynolds numbers. The transient combustion of 2-dimensionally arranged droplets, both the fixed droplet distances of 5 radii to 40 radii horizontally and 4 radii to 24 radii vertically, is studied. The results obtained from the present numerical analysis reveal that the transient flame configuration and retardation of droplet internal motion with the horizontal or vertical droplet spacing substantially influence lifetime of interacting droplets. At a low Reynolds number, lifetime of the two droplets with decreasing horizontal droplet spacing increases monotonically, whereas their lifetime with decreasing vertical droplet spacing decreases due to flow acceleration. This flow acceleration effect is reversed when the vertical droplet spacing is smaller than 5 radii in which decreasing flame penetration depth causes the reduction of heat transfer from flame to droplets. At a high Reynolds number, however, lifetime of the first droplet is hardly affected by either the horizontal droplet spacing or flow acceleration effect. Lifetime with decreasing vertical droplet spacing increases due to reduction of flame penetration depth. Lifetime of interacting droplets exhibits a strong dependence on Reynolds number, the horizontal droplet spacing and the vertical droplet spacing and can be con-elated well with these conditions to that of single burning droplet.
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A numerical study was conducted to determine the effects of high temperature air, including equivalent ratio on flow field, temperature, evaporation, and overall temperature distribution in gas turbine combustor. A sector model of a typical wall jet can combustor, featuring introduction of primary air and dilution air via wall jet, was used in calculations. Flow field and temperature distribution were analyzed. Operating conditions such as inlet temperature and overall equivalent ratio were varied from 373 to 1300 K, and from 0.3 to 0.6, respectively, while any other operating conditions were fixed. The RNG
${\kappa}-{\varepsilon}$ model and eddy breakup model were used for turbulence and combustion model respectively. It was found that the increase with the inlet air temperature, velocity in the combustor is accelerated and evaporation of liquid fuel is not affected in primary zone, high temperature inlet air enhances the evaporation and improves overall temperature distribution factor. -
In the multi-burner power plant, uneven supplies of combustion air to multi-burner are induced by unbalanced flow distribution in the windbox. These flow patterns tend to make flame unstable, increase the formation of pollutants and lower the overall combustion efficiency. To prevent these disadvantages, flow patterns in the windbox should be investigated and made to be distributed uniformly, In this study, scaled windbox model was used for tests and measured the velocities at the exit of the each burner and compared those with the CFD results.
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Extra heavy vacuum residue oil has advantage as the fuel of a power plant in reducing the cost of power generation. Numerical study is conducted by the KIVA code to understand combustion, heat transfer and flow field characteristics in the test reactor. The combustion model of pulverized coal particles is adopted as the combustion process of extra heavy oil is similar to that of coal. As an initial phase of investigation parametric study is performed with respect to SMD and spray angle of injected spray droplets.
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The TIER-LII system was established and evaluated using carbon black for diesel particulate size measurement. It contains a new designed sensor head which makes it easier to be measured. Through LII signal analysis of some parameters, we can understand that there were few correlations observed in effect of temperature, shield gas flow rate, and mixture flow rate.. However, an amount of difference was observed in different size of particulates.
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The thesis examined the charactcri:stlC of pollutants exhausted from LNG facilities. So, combustion gas and concentration of greenhouse gas exhausted from gas boiler for home use, furnace facilities, electric power facilities, boiler for industrial use and boiler for heating fueled LNG is measured. And the exhaust factor of pollutants is produced by classify of pollutants in detail. And this exhaust factor is compared and investigated with data of a foreign nations.
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For gaseous fuel combustion with inherent
$CO_2$ capture and low NOx emission, chemical-looping combustion(CLC) may yield great advantages of savings of energy to$CO_2$ separation and suppressing the effect on environment. In chemical-looping combustor, fuel is oxidized by metal oxide medium (oxygen carrier particle) in a reduction reactor. Reduced particles are transported to oxidation reactor and oxidized by air and recycled to reduction reactor. The fuel and the air are never mixed, and the gases from reduction reactor,$CO_2$ and$H_2O$ , leave the system as separate stream. The$H_2O$ can be easily separated by condensation and pure$CO_2$ is obtained without any loss of energy for separation. The purpose of this study is to demonstrate inherent$CO_2$ separation and no NOx emission and to confirm high$CO_2$ selectivity, no side reaction (i.e., carbon deposition, hydrogen generation) by continuous reduction and oxidation experiment in a 50kWtb chemical-looping combustor. NiO/bentonite particle was used as a bed material and$CH_4$ and air were used as reacting gases for reduction and oxidation respectively. -
Computations were performed to investigate the effects of air staging on combustion in three stage heavy-oil fired combustion burner. The burner was designed for 3 MW. Different amounts of air are introduced into each 3 three stages by means of each dampers. The goal of the study is to understand combustion phenomena according to each air stage mass ratios through CFD. Air flow rates at three inlets are adjusted by dampers inside a burner. Here, injection conditions of liquid fuel are kept constant throughout all simulations. This assumption is made in order to limit the complexity of oil combustion though it may cause some disagreement. In case of cold flows, only longitudinal velocities arc considered, On the other hand, flow, temperature and NOx generations are taken into account for reactive flows. Simple parametric study was conducted by setting 1'st air stage mass ratio as a parameter. And an optimal operation condition was found. The computational study is based on k-e model, P-1 radiation model(WSGGM) and PDF, and is implemented on a commercial code, FLUENT.
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An Experimental study was conducted on spray combustion using dual swirlers at different outlet angle; co-swirl and counter-swirl. To understand the characteristics of turbulent spray combustion of dual swirl flow (DSF), the axial helical annular vaned swirlers with various swirl ratios and combination of angle and direction were designed. and temperature measurements of a rapidly thermocouple insertion and measurements of soot volume fraction and microrstructure using thermophoretic sampling particle diagnostic (TSPD) as TEM were carried out. The NOx,
$CO_2$ ,$O_2$ , etc. was analyzed using emission gas analyzer. The results show that flame stability were maintained under very lean condition. for both co-swirl and counter-swirl case. And though Counter-swirl case kept the higher temperature region compared to co-swirl case, Counter-swirl combustion represented less NOx emission and soot formation than co-swirl case. -
For the compactness of regenerative combustion, self regenerative combustion and embedding regenerator inside furnace are proposed. The Self Regenerative burner system was developed to enhance thermal efficiency and Low Nox emission. In the twin regenerative system, two burner heads are generally used for preheating and exhausting combustion mode. But self regenerative burner system use only single nozzle body for regenerative combustion. Also two kind of regenerator, internal and external type, were designed to operate conveniently in both large and small furnace. According to test result, the self regenerative combustion system gives strong internal exhaust gas recirculation that reduce NOx emission significantly. NOx was measured as 50ppm(5% O2, 1290C furnace temperature). Also it is found that the fuel saving rate due to the self regenerative burner system reach to 30-40%. Thus it can be concluded that self regenerative mild combustion system appears to provide a reasonable regenerative burner for compactness and high performance as compared with conventional twin regenerative burner system. Also in the RT Application , compact twin regenerative burner was developed with the help of embedding regenerator inside furnace.
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콘덴싱보일러는 배기가스중의 수증기를 콘덴싱방식이라는 열교환 기술을 통해 2개의 열교환기에서 응축시키면서 생기는 응축잠열을 보일러에 더하여 줌으로써 기존보일러 대비 15
$^{\sim}$ 20% 이상 열효율이 높이는 첨단기술이 사용된 보일러로 콘덴싱보일러의 개발현황, 에너지 절감 효과 그리고 환경친화적 효과를 소개하고자 합니다. -
Mitsui Engineering and Shipbuilding Co., Ltd. (MES) has completed Recycling 21 (R21) pyrolysis and melting technology for municipal solid wastes. The basic technology is licensed from Siemens, but MES has made major improvements to the design and operation of the R21 system Consequently, up to now, MES has been completed six (6) R21 plants in Japan. The following text will provide a brief overview of the design & operating features of R21 technology, focused on the reliability of system and low emission of hazardous material, which have been proved by the successful construction & operation experience of the plants.