변형유기 식각 힐록 현상을 이용한 기계화학적 극미세 Writing 기법에 대한 연구

A Study of Mechanochemical Hyperfine-Writing Technique Using Deformation Induced Etch Hillock Phenomena

  • 강충길 (부산대학교 기계공학부) ;
  • 윤성원 (부산대학교 정밀기계공학과)
  • 발행 : 2005.07.01

초록

The purpose of this study is to suggest a hyperfine maskless writing technique by using the nanoindentation and HF wet etching technique. Indents were made on the surface of Pyrex7740 glass by the hyperfine indentation process with a Berkovich diamond indenter, and they were etched in $50\;wr\%$ HF solution. After etching process, convex structure was obtained due to the deformation-induced hillock phenomena. In this study, effects of indentation process parameters (etching time, normal load, loading .ate, hold-time at the maximum load) on the morphologies of the indented surfaces after isotopic etching were investigated from an angle of deformation energies. Finally, sample characters were written to show the possibility of the application.

키워드

참고문헌

  1. Chang, W.S., Shin, B.S., Whang, K.H., 'nanoprobe application technologies,' J Kor, Soc. Precis. Eng., Vol. 20, No.4, pp. 5-11, 2003
  2. Sung, I.H., Yang, J.C., Kim, D.E., Shin, B.S., 'Micro/nano-tribological characteristics of selfassembled monolayer and its application in nanostructure fabrication,' Wear, Vol. 255, pp. 808-818, 2003 https://doi.org/10.1016/S0043-1648(03)00058-9
  3. Wiesauer, K. and Springholz, G., 'Fabrication of semiconductor nanostructures by nanoindentation of photoresist layers using atomic force microscopy,' J Appl. Phys., Vol. 88, No. 12, pp.7289-7297, 2000 https://doi.org/10.1063/1.1324693
  4. Li, X., Gao, H., Murphy, C.J. and Caswell, K.K., 'Nanoindenttion of silver nanowires,' Nano letters, Vol. 3, No. 11, pp. 1495-1498, 2003 https://doi.org/10.1021/nl034525b
  5. Youn, S.W., Kang, C.G., 'Maskless pattern fabrication on pyrex 7740 glass surface by using nano-scratch with HF wet etching,' Scripta mater. 52, pp. 117-122, 2005 https://doi.org/10.1016/j.scriptamat.2004.09.016
  6. Youn, S.W., Kang, C.G., 'Maskless pattern fabrication on Si(100) surface by using nanoindenter with KOH wet etching,' Scripta mater. 50, pp. 105-109, 2004 https://doi.org/10.1016/j.scriptamat.2003.09.030
  7. Yoshino, M., Kitamura, G., Ogawa, Y, 'Ductile mode machining of hard-brittle materials under high hydrostatic pressure 92nd report) - machining test of hard-brittle materials under high hydrostatic pressure,' Jpn. Prec. Eng., Vol. 68, no. 10, pp. 1351-1355, 2002 https://doi.org/10.2493/jjspe.68.1351
  8. Kim, D.E., Yi, J.J, 'Micro-patterning of silicon by frictional interaction and chemical reaction,' J. Tribol.-T. ASME, 120, pp. 353, 1998 https://doi.org/10.1115/1.2834434
  9. Lee, J.J., Kim, D.E., 'A Novel Micro-Machining Technique Using Mechanical and Chemical Methods,' Transactions of KSME (A), Vol. 20, No. 10,pp.3113-3125, 1996
  10. Lang, W., 'Silicon microstructring technology,' Mater. Sci. & Eng., Vol. R17, pp. 1-55, 1996 https://doi.org/10.1016/0927-796X(96)00190-8
  11. Kovalchenko, A., Gogotsi, Y, Domnich, V., Erdemir, A., 'Phase transformations in silicon under dray and lubricated sliding,' Tribology transactions, Vol. 45, pp. 372-380, 2002 https://doi.org/10.1080/10402000208982562
  12. Ge, D., Domnich, V., Juliano, T., Stach, E.A., Gogotsi, Y, 'Structural damage in boron carbide under contact loading,' Acta mater., Vol. 52, pp. 3921-3927, 2004 https://doi.org/10.1016/j.actamat.2004.05.007
  13. Kim. J.J., Choi, Y, Suresh, S., Argon, S.S., 'Nanocrystallization during nanoindenation of a bulk amorphous metal alloy at room temperature,' Science, Vol. 295, No. 5555, pp. 654-657, 2002 https://doi.org/10.1126/science.1067453
  14. Ashida, K., Chen, L., Moria, N., 'New maskless micro-fabrication technique of single-crystal silicon using the combination of nanometer-scale machining and wet etching,' proc. of 2nd euspen Int., Conf., Turin, Italy, May, pp. 78-81, 2001
  15. Attaf, M.T., 'New ceramics related investigation of the indentation energy concept,' Materials letters, Vol. 57, pp. 4684-4693, 2003 https://doi.org/10.1016/S0167-577X(03)00375-6
  16. Bu, M., Melvin, T., Eensell G.J., Wilkinson, J.S., Evans, A.G.R., 'A new masking technology for deep glass etching and its microfluidic application,' Sensors and Actuators A, Vol. 115, pp. 476-482, 2004 https://doi.org/10.1016/j.sna.2003.12.013
  17. Avouris, Ph., Hertel, T. and Martel, R., 'Atomic force microscope tip-induced local oxidation of silicon: kinetics, mechanism, and nanofabrication,' Appl. Phys. Lett., Vol. 2, pp. 285-287, 1997 https://doi.org/10.1063/1.119521
  18. Anthony, C., Fischer-Cripps, 'Nanoindentation,' Springer- Velag, pp. 71-72, 2002
  19. Wu, H.E, Lin, C.C., Shen, P., 'Structure and dissolution of $CaO-ZrO_2-TiO_2-Al_2O_3-B_2O_3-SiO_2$ glass (II),' J. of Non-Crystalline Solids, Vol. 209, pp. 76-86, 1997 https://doi.org/10.1016/S0022-3093(96)00553-4
  20. Sigoli, EA., Kawano, Y., Davolos, M.R., Jafelicci Jr, M., 'Phase separation in Pyrex glass by hydrothermal treatment: evidence from micro-Roman spectroscopy,' J. of Non-Crystalline Solids, Vol. 284, pp. 49-54, 2001 https://doi.org/10.1016/S0022-3093(01)00378-7
  21. Youn, S.W., Kang, C.G., 2005, 'FEA study on nanodeformation behaviors of amorphous silicon and borosilicate considering tip geometry for pit array fabrication,' Materials Science and Engineering A, Vol. 319, pp. 233-239, 2005 https://doi.org/10.1016/j.msea.2004.08.041
  22. Elmustafa, A.A, Stone, D.S, 'Nanoindentation and the indentation size effect: kinetics of deformation and strain gradient plasticity,' J. Mechanics and Physics of Solids, Vol. 51, pp. 357-381, 2003 https://doi.org/10.1016/S0022-5096(02)00033-9
  23. Ichida, Y, Frej, N.B., Yousefi, R., 'Ductile-mode mirror cutting of single-crystal silicon (1st report) Effects of cutting speed on the brittle mode transition behavior in cutting process,' Jpn. Prec. Eng., Vol. 64, No.4, pp. 608-612, 1998 https://doi.org/10.2493/jjspe.64.608